Insight into the Structural and Emissive Behavior of a Three‐Dimensional Americium(III) Formate Coordination Polymer

We report the structural, vibrational, and optical properties of americium formate (Am(CHO2)3) crystals synthesized via the in situ hydrolysis of dimethylformamide (DMF). The coordination polymer features Am3+ ions linked by formate ligands into a three‐dimensional network that is isomorphous to sev...

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Veröffentlicht in:	Chemistry : a European journal 2023-07, Vol.29 (41), p.e202300077-n/a
Hauptverfasser:	Nicholas, Aaron D., Arteaga, Ana, Ducati, Lucas C., Buck, Edgar C., Autschbach, Jochen, Surbella, Robert G.
Format:	Artikel
Sprache:	eng
Schlagworte:	actinide chemistry Americium Bonding strength Chemistry coordination polymer Coordination polymers Crystals Dimethylformamide Emissions INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Ligands luminescence metal-organic frameworks Metals Molecular orbitals NLMO Optical properties Photoluminescence Photons Polymers QTAIM Quantum theory Spectroscopy transuranic
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