Impact of lanthanide ion complexation and temperature on the chemical reactivity of N , N , N ', N '-tetraoctyl diglycolamide (TODGA) with the dodecane radical cation

The impact of trivalent lanthanide ion complexation and temperature on the chemical reactivity of , , ', '-tetraoctyl diglycolamide (TODGA) with the -dodecane radical cation (RH˙ ) has been measured by electron pulse radiolysis and evaluated by quantum mechanical calculations. Additionally...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2023-06, Vol.25 (24), p.16404-16413
Hauptverfasser:	Horne, Gregory P, Celis-Barros, Cristian, Conrad, Jacy K, Grimes, Travis S, McLachlan, Jeffrey R, Rotermund, Brian M, Cook, Andrew R, Mezyk, Stephen P
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Atomic properties Cations Complex systems Complexation Dodecane Free energy Gadolinium Ligands Quantum mechanics Radicals Reactivity Ytterbium
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