Fluoro–nitrogen Cations
Abstract The crystal structures of [NH 3 F] + [CF 3 SO 3 ] − , [NH 2 F 2 ] + [SbF 6 ] − , and [N 2 F 3 ] + [Sb 3 F 16 ] − have been determined, representing the first structural characterizations of these simple fluoro‐nitrogen cations. The influences of the hybridization of the central nitrogen ato...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2021-12, Vol.61 (8) |
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| container_title | Angewandte Chemie (International ed.) |
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| creator | Vij, Ashwani Wilson, William W. Haiges, Ralf Edwards, Kyle C. Dixon, David A. Christe, Karl O. |
| description | Abstract
The crystal structures of [NH
3
F]
+
[CF
3
SO
3
]
−
, [NH
2
F
2
]
+
[SbF
6
]
−
, and [N
2
F
3
]
+
[Sb
3
F
16
]
−
have been determined, representing the first structural characterizations of these simple fluoro‐nitrogen cations. The influences of the hybridization of the central nitrogen atom and of the number of fluorine substituents on the N−F bond lengths are evaluated for the series N
2
F
+
, N
2
F
3
+
, NF
2
O
+
, NH
3
F
+
, NH
2
F
2
+
, and NF
4
+
. It is shown that the N−F bond length decreases from 1.40 Å to 1.26 Å with increasing fluorine substitution and increasing s‐character of the nitrogen atom, and that unusual N−F bond lengths reported in the previous literature are caused by disorder problems |
| format | Article |
| fullrecord | <record><control><sourceid>osti</sourceid><recordid>TN_cdi_osti_scitechconnect_1981387</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1981387</sourcerecordid><originalsourceid>FETCH-osti_scitechconnect_19813873</originalsourceid><addsrcrecordid>eNpjYuA0NDUy1DU2NzdmAbJNjI11zS1MDTkYuIqLswwMjCwsDMw4GSTdckrzi_IfNUzOyywpyk9PzVNwTizJzM8r5mFgTUvMKU7lhdLcDEpuriHOHrr5xSWZ8cXJmSWpyRnJ-Xl5qckl8YaWFobGFubGRCkCAI0WLQQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Fluoro–nitrogen Cations</title><source>Access via Wiley Online Library</source><creator>Vij, Ashwani ; Wilson, William W. ; Haiges, Ralf ; Edwards, Kyle C. ; Dixon, David A. ; Christe, Karl O.</creator><creatorcontrib>Vij, Ashwani ; Wilson, William W. ; Haiges, Ralf ; Edwards, Kyle C. ; Dixon, David A. ; Christe, Karl O. ; Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Catalysis Program</creatorcontrib><description>Abstract
The crystal structures of [NH
3
F]
+
[CF
3
SO
3
]
−
, [NH
2
F
2
]
+
[SbF
6
]
−
, and [N
2
F
3
]
+
[Sb
3
F
16
]
−
have been determined, representing the first structural characterizations of these simple fluoro‐nitrogen cations. The influences of the hybridization of the central nitrogen atom and of the number of fluorine substituents on the N−F bond lengths are evaluated for the series N
2
F
+
, N
2
F
3
+
, NF
2
O
+
, NH
3
F
+
, NH
2
F
2
+
, and NF
4
+
. It is shown that the N−F bond length decreases from 1.40 Å to 1.26 Å with increasing fluorine substitution and increasing s‐character of the nitrogen atom, and that unusual N−F bond lengths reported in the previous literature are caused by disorder problems</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><language>eng</language><publisher>United States: Wiley</publisher><subject>Chemistry ; fluoro-nitrogen ; fluoroammonium ; fluorodiazonium ; fluoronitronium ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; trifluoro-diazenium</subject><ispartof>Angewandte Chemie (International ed.), 2021-12, Vol.61 (8)</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000000306615519</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1981387$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Vij, Ashwani</creatorcontrib><creatorcontrib>Wilson, William W.</creatorcontrib><creatorcontrib>Haiges, Ralf</creatorcontrib><creatorcontrib>Edwards, Kyle C.</creatorcontrib><creatorcontrib>Dixon, David A.</creatorcontrib><creatorcontrib>Christe, Karl O.</creatorcontrib><creatorcontrib>Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Catalysis Program</creatorcontrib><title>Fluoro–nitrogen Cations</title><title>Angewandte Chemie (International ed.)</title><description>Abstract
The crystal structures of [NH
3
F]
+
[CF
3
SO
3
]
−
, [NH
2
F
2
]
+
[SbF
6
]
−
, and [N
2
F
3
]
+
[Sb
3
F
16
]
−
have been determined, representing the first structural characterizations of these simple fluoro‐nitrogen cations. The influences of the hybridization of the central nitrogen atom and of the number of fluorine substituents on the N−F bond lengths are evaluated for the series N
2
F
+
, N
2
F
3
+
, NF
2
O
+
, NH
3
F
+
, NH
2
F
2
+
, and NF
4
+
. It is shown that the N−F bond length decreases from 1.40 Å to 1.26 Å with increasing fluorine substitution and increasing s‐character of the nitrogen atom, and that unusual N−F bond lengths reported in the previous literature are caused by disorder problems</description><subject>Chemistry</subject><subject>fluoro-nitrogen</subject><subject>fluoroammonium</subject><subject>fluorodiazonium</subject><subject>fluoronitronium</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>trifluoro-diazenium</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpjYuA0NDUy1DU2NzdmAbJNjI11zS1MDTkYuIqLswwMjCwsDMw4GSTdckrzi_IfNUzOyywpyk9PzVNwTizJzM8r5mFgTUvMKU7lhdLcDEpuriHOHrr5xSWZ8cXJmSWpyRnJ-Xl5qckl8YaWFobGFubGRCkCAI0WLQQ</recordid><startdate>20211213</startdate><enddate>20211213</enddate><creator>Vij, Ashwani</creator><creator>Wilson, William W.</creator><creator>Haiges, Ralf</creator><creator>Edwards, Kyle C.</creator><creator>Dixon, David A.</creator><creator>Christe, Karl O.</creator><general>Wiley</general><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000000306615519</orcidid></search><sort><creationdate>20211213</creationdate><title>Fluoro–nitrogen Cations</title><author>Vij, Ashwani ; Wilson, William W. ; Haiges, Ralf ; Edwards, Kyle C. ; Dixon, David A. ; Christe, Karl O.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_19813873</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>fluoro-nitrogen</topic><topic>fluoroammonium</topic><topic>fluorodiazonium</topic><topic>fluoronitronium</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>trifluoro-diazenium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vij, Ashwani</creatorcontrib><creatorcontrib>Wilson, William W.</creatorcontrib><creatorcontrib>Haiges, Ralf</creatorcontrib><creatorcontrib>Edwards, Kyle C.</creatorcontrib><creatorcontrib>Dixon, David A.</creatorcontrib><creatorcontrib>Christe, Karl O.</creatorcontrib><creatorcontrib>Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Catalysis Program</creatorcontrib><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vij, Ashwani</au><au>Wilson, William W.</au><au>Haiges, Ralf</au><au>Edwards, Kyle C.</au><au>Dixon, David A.</au><au>Christe, Karl O.</au><aucorp>Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Catalysis Program</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluoro–nitrogen Cations</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><date>2021-12-13</date><risdate>2021</risdate><volume>61</volume><issue>8</issue><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Abstract
The crystal structures of [NH
3
F]
+
[CF
3
SO
3
]
−
, [NH
2
F
2
]
+
[SbF
6
]
−
, and [N
2
F
3
]
+
[Sb
3
F
16
]
−
have been determined, representing the first structural characterizations of these simple fluoro‐nitrogen cations. The influences of the hybridization of the central nitrogen atom and of the number of fluorine substituents on the N−F bond lengths are evaluated for the series N
2
F
+
, N
2
F
3
+
, NF
2
O
+
, NH
3
F
+
, NH
2
F
2
+
, and NF
4
+
. It is shown that the N−F bond length decreases from 1.40 Å to 1.26 Å with increasing fluorine substitution and increasing s‐character of the nitrogen atom, and that unusual N−F bond lengths reported in the previous literature are caused by disorder problems</abstract><cop>United States</cop><pub>Wiley</pub><orcidid>https://orcid.org/0000000306615519</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2021-12, Vol.61 (8) |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1981387 |
| source | Access via Wiley Online Library |
| subjects | Chemistry fluoro-nitrogen fluoroammonium fluorodiazonium fluoronitronium INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY trifluoro-diazenium |
| title | Fluoro–nitrogen Cations |
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