Mechanistic Investigation of Enhanced Catalytic Selectivity toward Alcohol Oxidation with Ce Oxysulfate Clusters

Ceria-based materials have been highly desired in photocatalytic reactions due to their redox properties and strong oxygen storage and transfer ability. Herein, we report the structures of one CeCe70 oxysulfate cluster and four MCe70 clusters (M = Cu, Ni, Co, and Fe) with the same Ce70 core. As note...

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Veröffentlicht in:	Journal of the American Chemical Society 2022-07, Vol.144 (27), p.12092-12101
Hauptverfasser:	Wang, Xingjie, Xie, Haomiao, Knapp, Julia G., Wasson, Megan C., Wu, Yufang, Ma, Kaikai, Stone, Aaron E.B.S., Krzyaniak, Matthew D., Chen, Yijing, Zhang, Xuan, Notestein, Justin M., Wasielewski, Michael R., Farha, Omar K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry
Online-Zugang:	Volltext
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