Diol isomer revealed as a source of methyl ketene from propionic acid unimolecular decomposition

Carboxylic acids are important combustion intermediates, especially regarding the combustion of oxygenates such as ethyl esters. The purpose of this study is to discern the unimolecular decomposition pathways of one such carboxylic acid, propionic acid, using microreactor flow experiments with line‐...

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Veröffentlicht in:	International journal of chemical kinetics 2021-12, Vol.53 (12), p.1272-1284
Hauptverfasser:	Rogers, Cory O., Lockwood, Katherine S., Nguyen, Quynh L. D., Labbe, Nicole J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Carboxylic acids Chemical products Combustion Decarboxylation Decomposition Dehydrogenation diols Electronic structure Ethyl esters Ethylene Infrared spectroscopy INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Isomerization Mass spectrometry Methyl radicals microreactor Microreactors Photoionization Propionic acid pyrolysis kinetics Rate constants Skips Thermal decomposition
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