Enhancement of Emission from Lanthanide Dopants in Perovskite Nanocrystals through a Temperature-Dependent Phase Transformation of the Perovskite Lattice

Enhancement of Emission from Lanthanide Dopants in Perovskite Nanocrystals through a Temperature-Dependent Phase Transformation of the Perovskite Lattice

The excited states of lanthanide ions (Ln3+) exhibit ultranarrow emission and long spin dephasing lifetimes suitable for optoelectronic and quantum applications but are not directly optically accessible. One effective strategy to excite Ln3+ ions is to dope them into a semiconductor host lattice, wh...

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Veröffentlicht in:Journal of physical chemistry. C 2022-09, Vol.126 (36), p.15247-15253
Hauptverfasser: Chang, Woo Je, Irgen-Gioro, Shawn, Vong, Albert F., Kim, Hacksung, Mara, Michael W., Chen, Lin X., Weiss, Emily A.
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INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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container_end_page 15253
container_issue 36
container_start_page 15247
container_title Journal of physical chemistry. C
container_volume 126
creator Chang, Woo Je
Irgen-Gioro, Shawn
Vong, Albert F.
Kim, Hacksung
Mara, Michael W.
Chen, Lin X.
Weiss, Emily A.
description The excited states of lanthanide ions (Ln3+) exhibit ultranarrow emission and long spin dephasing lifetimes suitable for optoelectronic and quantum applications but are not directly optically accessible. One effective strategy to excite Ln3+ ions is to dope them into a semiconductor host lattice, which acts as a photosensitizer. This work describes enhancement of emission intensity by a factor of 19 with decreasing temperature (from 300 to S K) from Sm3+ ions in CsPbCl3 nanocrystal hosts. Structural characterization over the same temperature region reveals that this enhancement is primarily due to a symmetry-lowering cubic-to-orthorhombic phase transition of the host lattice, which reduces the local site symmetry of the dopant and increases the Sm3+* emission quantum yield.
doi_str_mv 10.1021/acs.jpcc.2c03189
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title Enhancement of Emission from Lanthanide Dopants in Perovskite Nanocrystals through a Temperature-Dependent Phase Transformation of the Perovskite Lattice
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