Ligand-coordination effects on the selective hydrogenation of acetylene in single-site Pd-ligand supported catalysts

The selective hydrogenation of acetylene to ethylene is a critical step in the synthesis of polyethylenes. Achieving high conversion to ethylene without over-hydrogenation to ethane is a challenge that requires control of the transition metal site, which we achieve through a ligand-coordinated suppo...

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Veröffentlicht in:	Journal of catalysis 2022-06, Vol.413
Hauptverfasser:	Wasim, Eman, Din, Naseem Ud, Le, Duy, Zhou, Xuemei, Sterbinsky, George E., Pape, Michael S., Rahman, Talat S., Tait, Steven L.
Format:	Artikel
Sprache:	eng
Schlagworte:	density functional theory extended X-ray absorption fine structure spectroscopy INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ligand coordinated single site catalysts Pd selective hydrogenation of acetylene x-ray photoelectron spectroscopy
Online-Zugang:	Volltext
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