Trapping of a Late-Metal Terminal Sulfido Intermediate with Phenyl Isothiocyanate

Nickel–sulfur bonds play key roles in catalysis and biological systems. In most metal complexes, sulfur acts as a bridge joining metal centers, rather than as a terminal sulfide ligand. The addition of phenyl isothiocyanate to Ni­(dcpe)­(Ph)­(SH) afforded the dithiocarbamate complex Ni­(dcpe)­(κ2-S2...

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Veröffentlicht in:	Organometallics 2022-11, Vol.41 (22), p.3448-3453
Hauptverfasser:	Shanahan, James P., Vicic, David A., Brennessel, William W., Jones, William D.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactions Kinetics Ligands Organic reactions Phenyls
Online-Zugang:	Volltext
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