Monofluorination of Naphthyls Promotes the Cofacial π–π Stacking and Increases the Electron Mobility of Non-Planar Zinc(II) Complexes of Di(naphthylethynyl)azadipyrromethene

The homoleptic zinc­(II) complex of [2,8-di­(1-naphthylethynyl) 3,7-diphenyl 1,9-(4-hexylphenyl)­azadipyrromethene (ZnL2)2] is a promising non-planar non-fullerene acceptor for organic photovoltaic applications, but it has a relatively low electron mobility that may limit its performance. Here, we e...

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Veröffentlicht in:	Journal of physical chemistry. C 2022-04, Vol.126 (15), p.6543-6555
Hauptverfasser:	Zhao, Muyuan, Jimenez, Jayvic C, Wang, Chunlai, Rui, Guanchun, Ma, Tingrui, Lu, Chenwei, Rheingold, Arnold L, Li, Ruipeng, Zhu, Lei, Sauvé, Geneviève
Format:	Artikel
Sprache:	eng
Schlagworte:	C: Energy Conversion and Storage charge transport halogenation MATERIALS SCIENCE mobility molecules organic polymers
Online-Zugang:	Volltext
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