On the Effects of Aliovalent Substitutions in Thermoelectric Zintl Pnictides. Varied Polyanionic Dimensionality and Complex Structural Transformations–The Case of Sr3ZnP3 vs Sr3AlxZn1–xP3

The structures and the transport properties of a novel family of Zintl phosphides and arsenides with the formula AE3ZnPn3 and the solid solutions AE3AlxZn1–xPn3, AE3ZnAsyP1–y (AE = Sr, Eu; Pn = P, As) are reported. Crystals of nine new phases have been obtained via Pb-flux reactions and used for str...

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Veröffentlicht in:	Chemistry of materials 2022-04, Vol.34 (9)
Hauptverfasser:	Baranets, Sviatoslav, Balvanz, Adam, Darone, Gregory M., Bobev, Svilen
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical structure Crystal structure Crystals Diseases and disorders INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE Pnictides
Online-Zugang:	Volltext
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