In situ and ex situ studies of anomalous eutectic formation in undercooled Ni–Sn alloys
Anomalous eutectic formation in undercooled Ni–Sn alloys was investigated by in situ X-ray diffraction and ex situ remelting and annealing experiments. Dynamic recrystallization and partial remelting of primary solids followed by repeated nucleation and growth of eutectic grains in the mushy zone we...
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Veröffentlicht in: | Acta materialia 2020-09, Vol.197 (C), p.198-211 |
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creator | Zhao, Rijie Wang, Yeqing Gao, Jianrong Baker, Evan B. Matson, Douglas M. Kolbe, Matthias Chuang, Andrew Chih-Pin Ren, Yang |
description | Anomalous eutectic formation in undercooled Ni–Sn alloys was investigated by in situ X-ray diffraction and ex situ remelting and annealing experiments. Dynamic recrystallization and partial remelting of primary solids followed by repeated nucleation and growth of eutectic grains in the mushy zone were revealed by time-resolved X-ray diffraction. Ex situ experiments demonstrated that partial remelting of near-equilibrium solidified alloys of eutectic or near-eutectic composition can convert regular lamellar eutectic into anomalous eutectic, whereas high-temperature annealing of splat-quenched alloys of similar composition can convert eutectic or two-phase dendrites into anomalous eutectic. It is concluded that compared to ripening in solid-states, partial remelting of eutectic or two-phase dendrites in a mushy zone provides a more realistic mechanism for anomalous eutectic formation in undercooled solidification of Ni–Sn eutectic alloys.
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doi_str_mv | 10.1016/j.actamat.2020.07.048 |
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[Display omitted]</description><subject>Crystal growth</subject><subject>Eutectic</subject><subject>Solidification microstructure</subject><subject>Undercooling</subject><subject>X-ray diffraction</subject><issn>1359-6454</issn><issn>1873-2453</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKxDAUhoMoOF4eQQjuW3Nt05XI4GVg0IW6cBXSJMUMnUSaVJyd7-Ab-iSmdPauzuFw_v_85wPgAqMSI1xdbUqlk9qqVBJEUInqEjFxABZY1LQgjNPD3FPeFBXj7BicxLhBCJOaoQV4W3kYXRqh8gbar7mPaTTORhi6PA5b1YcxQjsmq5PTsAtDvuWCh87D0Rs76BB6a-Cj-_3-efZQ9X3YxTNw1Kk-2vN9PQWvd7cvy4di_XS_Wt6sC01plYqaCUZsx0xrcnjcsArTrhGk1Q0npKtrIgRXnFJLGtRQjJCxAk2SVincGnoKLmffEJOTUbsc810H73NamRFwLnBe4vOSHkKMg-3kx-C2athJjOQEUW7kHqKcIEpUywwx665nnc0ffDo7TAes19a4YfI3wf3j8Aefx343</recordid><startdate>20200915</startdate><enddate>20200915</enddate><creator>Zhao, Rijie</creator><creator>Wang, Yeqing</creator><creator>Gao, Jianrong</creator><creator>Baker, Evan B.</creator><creator>Matson, Douglas M.</creator><creator>Kolbe, Matthias</creator><creator>Chuang, Andrew Chih-Pin</creator><creator>Ren, Yang</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0003-1160-6553</orcidid><orcidid>https://orcid.org/0000000311606553</orcidid></search><sort><creationdate>20200915</creationdate><title>In situ and ex situ studies of anomalous eutectic formation in undercooled Ni–Sn alloys</title><author>Zhao, Rijie ; Wang, Yeqing ; Gao, Jianrong ; Baker, Evan B. ; Matson, Douglas M. ; Kolbe, Matthias ; Chuang, Andrew Chih-Pin ; Ren, Yang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c336t-74842ef4dbd020194613f982bc9522f772885a533e29093100de8042efbaa1bd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Crystal growth</topic><topic>Eutectic</topic><topic>Solidification microstructure</topic><topic>Undercooling</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Rijie</creatorcontrib><creatorcontrib>Wang, Yeqing</creatorcontrib><creatorcontrib>Gao, Jianrong</creatorcontrib><creatorcontrib>Baker, Evan B.</creatorcontrib><creatorcontrib>Matson, Douglas M.</creatorcontrib><creatorcontrib>Kolbe, Matthias</creatorcontrib><creatorcontrib>Chuang, Andrew Chih-Pin</creatorcontrib><creatorcontrib>Ren, Yang</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Acta materialia</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Rijie</au><au>Wang, Yeqing</au><au>Gao, Jianrong</au><au>Baker, Evan B.</au><au>Matson, Douglas M.</au><au>Kolbe, Matthias</au><au>Chuang, Andrew Chih-Pin</au><au>Ren, Yang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ and ex situ studies of anomalous eutectic formation in undercooled Ni–Sn alloys</atitle><jtitle>Acta materialia</jtitle><date>2020-09-15</date><risdate>2020</risdate><volume>197</volume><issue>C</issue><spage>198</spage><epage>211</epage><pages>198-211</pages><issn>1359-6454</issn><eissn>1873-2453</eissn><abstract>Anomalous eutectic formation in undercooled Ni–Sn alloys was investigated by in situ X-ray diffraction and ex situ remelting and annealing experiments. Dynamic recrystallization and partial remelting of primary solids followed by repeated nucleation and growth of eutectic grains in the mushy zone were revealed by time-resolved X-ray diffraction. Ex situ experiments demonstrated that partial remelting of near-equilibrium solidified alloys of eutectic or near-eutectic composition can convert regular lamellar eutectic into anomalous eutectic, whereas high-temperature annealing of splat-quenched alloys of similar composition can convert eutectic or two-phase dendrites into anomalous eutectic. It is concluded that compared to ripening in solid-states, partial remelting of eutectic or two-phase dendrites in a mushy zone provides a more realistic mechanism for anomalous eutectic formation in undercooled solidification of Ni–Sn eutectic alloys.
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subjects | Crystal growth Eutectic Solidification microstructure Undercooling X-ray diffraction |
title | In situ and ex situ studies of anomalous eutectic formation in undercooled Ni–Sn alloys |
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