In situ and ex situ studies of anomalous eutectic formation in undercooled Ni–Sn alloys

Anomalous eutectic formation in undercooled Ni–Sn alloys was investigated by in situ X-ray diffraction and ex situ remelting and annealing experiments. Dynamic recrystallization and partial remelting of primary solids followed by repeated nucleation and growth of eutectic grains in the mushy zone we...

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Veröffentlicht in:Acta materialia 2020-09, Vol.197 (C), p.198-211
Hauptverfasser: Zhao, Rijie, Wang, Yeqing, Gao, Jianrong, Baker, Evan B., Matson, Douglas M., Kolbe, Matthias, Chuang, Andrew Chih-Pin, Ren, Yang
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container_end_page 211
container_issue C
container_start_page 198
container_title Acta materialia
container_volume 197
creator Zhao, Rijie
Wang, Yeqing
Gao, Jianrong
Baker, Evan B.
Matson, Douglas M.
Kolbe, Matthias
Chuang, Andrew Chih-Pin
Ren, Yang
description Anomalous eutectic formation in undercooled Ni–Sn alloys was investigated by in situ X-ray diffraction and ex situ remelting and annealing experiments. Dynamic recrystallization and partial remelting of primary solids followed by repeated nucleation and growth of eutectic grains in the mushy zone were revealed by time-resolved X-ray diffraction. Ex situ experiments demonstrated that partial remelting of near-equilibrium solidified alloys of eutectic or near-eutectic composition can convert regular lamellar eutectic into anomalous eutectic, whereas high-temperature annealing of splat-quenched alloys of similar composition can convert eutectic or two-phase dendrites into anomalous eutectic. It is concluded that compared to ripening in solid-states, partial remelting of eutectic or two-phase dendrites in a mushy zone provides a more realistic mechanism for anomalous eutectic formation in undercooled solidification of Ni–Sn eutectic alloys. [Display omitted]
doi_str_mv 10.1016/j.actamat.2020.07.048
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subjects Crystal growth
Eutectic
Solidification microstructure
Undercooling
X-ray diffraction
title In situ and ex situ studies of anomalous eutectic formation in undercooled Ni–Sn alloys
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