Tuneable phase behaviour and glass transition via polymerization-induced phase separation in crosslinked step-growth polymers

Once limited to chain-growth polymerizations, fine control over polymerization-induced phase separation (PIPS) has recently been demonstrated in rubber-toughened thermoset materials formed through step-growth polymerizations. The domain length scales of these thermoset materials can be elegantly tun...

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Veröffentlicht in:	Soft matter 2022-06, Vol.18 (23), p.4455-4463
Hauptverfasser:	Leguizamon, Samuel C, Ahn, Juhong, Lee, Sangwoo, Jones, Brad H
Format:	Artikel
Sprache:	eng
Schlagworte:	Binary mixtures Crosslinking Curing agents Glass transition temperature Morphology Phase diagrams Phase separation Polymerization Polymers Rubber Transition temperatures X-ray scattering
Online-Zugang:	Volltext
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