Homoleptic Perchlorophenyl “Ate” Complexes of Thorium(IV) and Uranium(IV)

The reaction of AnCl4(DME)n (An = Th, n = 2; U, n = 0) with 5 equiv of LiC6Cl5 in Et2O resulted in the formation of homoleptic actinide-aryl “ate” complexes [Li(DME)2(Et2O)]2[Li(DME)2][Th(C6Cl5)5]3 ([Li][1]) and [Li(Et2O)4][U(C6Cl5)5] ([Li][2]). Similarly, the reaction of AnCl4(DME)n (An = Th, n = 2...

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Veröffentlicht in:	Inorganic chemistry 2021-07, Vol.60 (16)
Hauptverfasser:	Ordoñez, Osvaldo, Yu, Xiaojuan, Wu, Guang, Autschbach, Jochen, Hayton, Trevor W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Actinides INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Ligands Mathematical methods Thorium Uranium
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