Ion-pair reorganization regulates reactivity in photoredox catalysts

Cyclometalated and polypyridyl complexes of d 6 metals are promising photoredox catalysts, using light to drive reactions with high kinetic or thermodynamic barriers via the generation of reactive radical intermediates. However, while tuning of their redox potentials, absorption energy, excited-stat...

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Veröffentlicht in:	Nature chemistry 2022-07, Vol.14 (7), p.746-753
Hauptverfasser:	Earley, J. D., Zieleniewska, A., Ripberger, H. H., Shin, N. Y., Lazorski, M. S., Mast, Z. J., Sayre, H. J., McCusker, J. K., Scholes, G. D., Knowles, R. R., Reid, O. G., Rumbles, G.
Format:	Artikel
Sprache:	eng
Schlagworte:	639/638/263/406/939 639/638/439/890 639/638/440/949 639/638/77/890 Analytical Chemistry Biochemistry Catalysts Charge distribution Chemistry Chemistry and Materials Science Chemistry/Food Science CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS Dipole moments Electron transfer Excitation Inorganic Chemistry INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Intermediates ion pairing Ion pairs Ligands Metals Organic Chemistry OTHER INSTRUMENTATION Oxidation Photocatalysis Photoredox catalysis Physical Chemistry Reactivity Selectivity Solvents Time-resolved dielectric-loss (TRDL) spectroscopy
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