Electrocatalytic Reduction of C–C π‑Bonds via a Cobaltocene-Derived Concerted Proton–Electron Transfer Mediator: Fumarate Hydrogenation as a Model Study

Reductive concerted proton–electron transfer (CPET) is poorly developed for the reduction of C–C π-bonds, including for activated alkenes that can succumb to deleterious pathways (e.g., a competing hydrogen evolution reaction or oligomerization) in a standard electrochemical reduction. We demonstrat...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-06, Vol.143 (25), p.9303-9307
Hauptverfasser:	Derosa, Joseph, Garrido-Barros, Pablo, Peters, Jonas C
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry
Online-Zugang:	Volltext
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