Interfacial Compatibilization in Ternary Polymer Nanocomposites: Comparing Theory and Experiments
In this work, we examine binary and ternary nanocomposites of poly(methyl methacrylate) grafted silica nanoparticles (PMMA-NP), in poly(styrene-ran-acrylonitrile) (SAN), and poly(methyl methacrylate) matrices as a platform to directly probe governing parameters guiding phase behavior and nanopart...
Gespeichert in:
| Veröffentlicht in: | Macromolecules 2021-01, Vol.54 (2), p.797-811 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 811 |
|---|---|
| container_issue | 2 |
| container_start_page | 797 |
| container_title | Macromolecules |
| container_volume | 54 |
| creator | Maguire, Shawn M Krook, Nadia M Kulshreshtha, Arjita Bilchak, Connor R Brosnan, Robert Pana, Andreea-Maria Rannou, Patrice Maréchal, Manuel Ohno, Kohji Jayaraman, Arthi Composto, Russell J |
| description | In this work, we examine binary and ternary nanocomposites of poly(methyl methacrylate) grafted silica nanoparticles (PMMA-NP), in poly(styrene-ran-acrylonitrile) (SAN), and poly(methyl methacrylate) matrices as a platform to directly probe governing parameters guiding phase behavior and nanoparticle assembly in composite materials. Through the addition of PMMA matrix chains similar in molecular weight to the grafted PMMA chains and significantly smaller than the SAN matrix chains, we observe increased nanoparticle miscibility in off-critical compositions due to interfacial segregation of PMMA matrix chains. A simple interfacial model provides a general guideline for predicting the extent of compatibilization. Further insights on compatibilization behavior are provided by polymer particle pair correlation functions and structure factors obtained using polymer reference interaction site model theory calculations as well as polymer concentration profiles from molecular dynamics simulations. This study serves as a guideline to facilitate PNC processing and design of materials for a broad range of technological applications. |
| doi_str_mv | 10.1021/acs.macromol.0c02345 |
| format | Article |
| fullrecord | <record><control><sourceid>acs_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_1852414</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>i32538192</sourcerecordid><originalsourceid>FETCH-LOGICAL-a465t-e5452b27570bbd5a35df6c0179fe38d1b84110e725a2bc2494518d6691b60ff83</originalsourceid><addsrcrecordid>eNp9kLtOwzAUQC0EEqXwBwwRG0PKvX7kwYYqoEgVMJTZchyHukrsKg6I8vW4SmFkupJ9jnV9CLlEmCFQvFE6zDqle9_5dgYaKOPiiExQUEhFwcQxmQBQnpa0zE_JWQgbAETB2YSoJzeYvlHaqjaZ-26rBlvZ1n7H6V1iXbIyvVP9Lnn17a4zffKsnNcR9MEOJtyOUm_de7JaGx9B5erk_mtretsZN4RzctKoNpiLw5ySt4f71XyRLl8en-Z3y1TxTAypEVzQiuYih6qqhWKibjINmJeNYUWNVcERweRUKFppyksusKizrMQqg6Yp2JRcje_6MFgZdNxOr7V3zuhBYiEoRx6h6xFaq1Zu44bxZ9IrKxd3S7k_A8YpgxI-MbJ8ZGPYEHrT_AkIct9dxu7yt7s8dI8ajNr-duM_Yr02_K_8ACgZioc</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Interfacial Compatibilization in Ternary Polymer Nanocomposites: Comparing Theory and Experiments</title><source>ACS Publications</source><creator>Maguire, Shawn M ; Krook, Nadia M ; Kulshreshtha, Arjita ; Bilchak, Connor R ; Brosnan, Robert ; Pana, Andreea-Maria ; Rannou, Patrice ; Maréchal, Manuel ; Ohno, Kohji ; Jayaraman, Arthi ; Composto, Russell J</creator><creatorcontrib>Maguire, Shawn M ; Krook, Nadia M ; Kulshreshtha, Arjita ; Bilchak, Connor R ; Brosnan, Robert ; Pana, Andreea-Maria ; Rannou, Patrice ; Maréchal, Manuel ; Ohno, Kohji ; Jayaraman, Arthi ; Composto, Russell J ; Univ. of Delaware, Newark, DE (United States)</creatorcontrib><description>In this work, we examine binary and ternary nanocomposites of poly(methyl methacrylate) grafted silica nanoparticles (PMMA-NP), in poly(styrene-ran-acrylonitrile) (SAN), and poly(methyl methacrylate) matrices as a platform to directly probe governing parameters guiding phase behavior and nanoparticle assembly in composite materials. Through the addition of PMMA matrix chains similar in molecular weight to the grafted PMMA chains and significantly smaller than the SAN matrix chains, we observe increased nanoparticle miscibility in off-critical compositions due to interfacial segregation of PMMA matrix chains. A simple interfacial model provides a general guideline for predicting the extent of compatibilization. Further insights on compatibilization behavior are provided by polymer particle pair correlation functions and structure factors obtained using polymer reference interaction site model theory calculations as well as polymer concentration profiles from molecular dynamics simulations. This study serves as a guideline to facilitate PNC processing and design of materials for a broad range of technological applications.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/acs.macromol.0c02345</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Chemical Sciences ; Material chemistry ; Polymer Science</subject><ispartof>Macromolecules, 2021-01, Vol.54 (2), p.797-811</ispartof><rights>2021 American Chemical Society</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a465t-e5452b27570bbd5a35df6c0179fe38d1b84110e725a2bc2494518d6691b60ff83</citedby><cites>FETCH-LOGICAL-a465t-e5452b27570bbd5a35df6c0179fe38d1b84110e725a2bc2494518d6691b60ff83</cites><orcidid>0000-0003-3308-9040 ; 0000-0002-5295-4581 ; 0000-0001-8815-1601 ; 0000-0001-9376-7136 ; 0000-0002-1812-3354 ; 0000-0002-5906-2594 ; 0000-0002-4295-7244 ; 0000-0002-5317-4990 ; 0000000333089040 ; 0000000218123354 ; 0000000188151601 ; 0000000252954581 ; 0000000259062594 ; 0000000193767136</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.macromol.0c02345$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.macromol.0c02345$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03423090$$DView record in HAL$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1852414$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Maguire, Shawn M</creatorcontrib><creatorcontrib>Krook, Nadia M</creatorcontrib><creatorcontrib>Kulshreshtha, Arjita</creatorcontrib><creatorcontrib>Bilchak, Connor R</creatorcontrib><creatorcontrib>Brosnan, Robert</creatorcontrib><creatorcontrib>Pana, Andreea-Maria</creatorcontrib><creatorcontrib>Rannou, Patrice</creatorcontrib><creatorcontrib>Maréchal, Manuel</creatorcontrib><creatorcontrib>Ohno, Kohji</creatorcontrib><creatorcontrib>Jayaraman, Arthi</creatorcontrib><creatorcontrib>Composto, Russell J</creatorcontrib><creatorcontrib>Univ. of Delaware, Newark, DE (United States)</creatorcontrib><title>Interfacial Compatibilization in Ternary Polymer Nanocomposites: Comparing Theory and Experiments</title><title>Macromolecules</title><addtitle>Macromolecules</addtitle><description>In this work, we examine binary and ternary nanocomposites of poly(methyl methacrylate) grafted silica nanoparticles (PMMA-NP), in poly(styrene-ran-acrylonitrile) (SAN), and poly(methyl methacrylate) matrices as a platform to directly probe governing parameters guiding phase behavior and nanoparticle assembly in composite materials. Through the addition of PMMA matrix chains similar in molecular weight to the grafted PMMA chains and significantly smaller than the SAN matrix chains, we observe increased nanoparticle miscibility in off-critical compositions due to interfacial segregation of PMMA matrix chains. A simple interfacial model provides a general guideline for predicting the extent of compatibilization. Further insights on compatibilization behavior are provided by polymer particle pair correlation functions and structure factors obtained using polymer reference interaction site model theory calculations as well as polymer concentration profiles from molecular dynamics simulations. This study serves as a guideline to facilitate PNC processing and design of materials for a broad range of technological applications.</description><subject>Chemical Sciences</subject><subject>Material chemistry</subject><subject>Polymer Science</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kLtOwzAUQC0EEqXwBwwRG0PKvX7kwYYqoEgVMJTZchyHukrsKg6I8vW4SmFkupJ9jnV9CLlEmCFQvFE6zDqle9_5dgYaKOPiiExQUEhFwcQxmQBQnpa0zE_JWQgbAETB2YSoJzeYvlHaqjaZ-26rBlvZ1n7H6V1iXbIyvVP9Lnn17a4zffKsnNcR9MEOJtyOUm_de7JaGx9B5erk_mtretsZN4RzctKoNpiLw5ySt4f71XyRLl8en-Z3y1TxTAypEVzQiuYih6qqhWKibjINmJeNYUWNVcERweRUKFppyksusKizrMQqg6Yp2JRcje_6MFgZdNxOr7V3zuhBYiEoRx6h6xFaq1Zu44bxZ9IrKxd3S7k_A8YpgxI-MbJ8ZGPYEHrT_AkIct9dxu7yt7s8dI8ajNr-duM_Yr02_K_8ACgZioc</recordid><startdate>20210126</startdate><enddate>20210126</enddate><creator>Maguire, Shawn M</creator><creator>Krook, Nadia M</creator><creator>Kulshreshtha, Arjita</creator><creator>Bilchak, Connor R</creator><creator>Brosnan, Robert</creator><creator>Pana, Andreea-Maria</creator><creator>Rannou, Patrice</creator><creator>Maréchal, Manuel</creator><creator>Ohno, Kohji</creator><creator>Jayaraman, Arthi</creator><creator>Composto, Russell J</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0003-3308-9040</orcidid><orcidid>https://orcid.org/0000-0002-5295-4581</orcidid><orcidid>https://orcid.org/0000-0001-8815-1601</orcidid><orcidid>https://orcid.org/0000-0001-9376-7136</orcidid><orcidid>https://orcid.org/0000-0002-1812-3354</orcidid><orcidid>https://orcid.org/0000-0002-5906-2594</orcidid><orcidid>https://orcid.org/0000-0002-4295-7244</orcidid><orcidid>https://orcid.org/0000-0002-5317-4990</orcidid><orcidid>https://orcid.org/0000000333089040</orcidid><orcidid>https://orcid.org/0000000218123354</orcidid><orcidid>https://orcid.org/0000000188151601</orcidid><orcidid>https://orcid.org/0000000252954581</orcidid><orcidid>https://orcid.org/0000000259062594</orcidid><orcidid>https://orcid.org/0000000193767136</orcidid></search><sort><creationdate>20210126</creationdate><title>Interfacial Compatibilization in Ternary Polymer Nanocomposites: Comparing Theory and Experiments</title><author>Maguire, Shawn M ; Krook, Nadia M ; Kulshreshtha, Arjita ; Bilchak, Connor R ; Brosnan, Robert ; Pana, Andreea-Maria ; Rannou, Patrice ; Maréchal, Manuel ; Ohno, Kohji ; Jayaraman, Arthi ; Composto, Russell J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a465t-e5452b27570bbd5a35df6c0179fe38d1b84110e725a2bc2494518d6691b60ff83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical Sciences</topic><topic>Material chemistry</topic><topic>Polymer Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maguire, Shawn M</creatorcontrib><creatorcontrib>Krook, Nadia M</creatorcontrib><creatorcontrib>Kulshreshtha, Arjita</creatorcontrib><creatorcontrib>Bilchak, Connor R</creatorcontrib><creatorcontrib>Brosnan, Robert</creatorcontrib><creatorcontrib>Pana, Andreea-Maria</creatorcontrib><creatorcontrib>Rannou, Patrice</creatorcontrib><creatorcontrib>Maréchal, Manuel</creatorcontrib><creatorcontrib>Ohno, Kohji</creatorcontrib><creatorcontrib>Jayaraman, Arthi</creatorcontrib><creatorcontrib>Composto, Russell J</creatorcontrib><creatorcontrib>Univ. of Delaware, Newark, DE (United States)</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><collection>OSTI.GOV</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maguire, Shawn M</au><au>Krook, Nadia M</au><au>Kulshreshtha, Arjita</au><au>Bilchak, Connor R</au><au>Brosnan, Robert</au><au>Pana, Andreea-Maria</au><au>Rannou, Patrice</au><au>Maréchal, Manuel</au><au>Ohno, Kohji</au><au>Jayaraman, Arthi</au><au>Composto, Russell J</au><aucorp>Univ. of Delaware, Newark, DE (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interfacial Compatibilization in Ternary Polymer Nanocomposites: Comparing Theory and Experiments</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>2021-01-26</date><risdate>2021</risdate><volume>54</volume><issue>2</issue><spage>797</spage><epage>811</epage><pages>797-811</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><abstract>In this work, we examine binary and ternary nanocomposites of poly(methyl methacrylate) grafted silica nanoparticles (PMMA-NP), in poly(styrene-ran-acrylonitrile) (SAN), and poly(methyl methacrylate) matrices as a platform to directly probe governing parameters guiding phase behavior and nanoparticle assembly in composite materials. Through the addition of PMMA matrix chains similar in molecular weight to the grafted PMMA chains and significantly smaller than the SAN matrix chains, we observe increased nanoparticle miscibility in off-critical compositions due to interfacial segregation of PMMA matrix chains. A simple interfacial model provides a general guideline for predicting the extent of compatibilization. Further insights on compatibilization behavior are provided by polymer particle pair correlation functions and structure factors obtained using polymer reference interaction site model theory calculations as well as polymer concentration profiles from molecular dynamics simulations. This study serves as a guideline to facilitate PNC processing and design of materials for a broad range of technological applications.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/acs.macromol.0c02345</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-3308-9040</orcidid><orcidid>https://orcid.org/0000-0002-5295-4581</orcidid><orcidid>https://orcid.org/0000-0001-8815-1601</orcidid><orcidid>https://orcid.org/0000-0001-9376-7136</orcidid><orcidid>https://orcid.org/0000-0002-1812-3354</orcidid><orcidid>https://orcid.org/0000-0002-5906-2594</orcidid><orcidid>https://orcid.org/0000-0002-4295-7244</orcidid><orcidid>https://orcid.org/0000-0002-5317-4990</orcidid><orcidid>https://orcid.org/0000000333089040</orcidid><orcidid>https://orcid.org/0000000218123354</orcidid><orcidid>https://orcid.org/0000000188151601</orcidid><orcidid>https://orcid.org/0000000252954581</orcidid><orcidid>https://orcid.org/0000000259062594</orcidid><orcidid>https://orcid.org/0000000193767136</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0024-9297 |
| ispartof | Macromolecules, 2021-01, Vol.54 (2), p.797-811 |
| issn | 0024-9297 1520-5835 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1852414 |
| source | ACS Publications |
| subjects | Chemical Sciences Material chemistry Polymer Science |
| title | Interfacial Compatibilization in Ternary Polymer Nanocomposites: Comparing Theory and Experiments |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T17%3A11%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Interfacial%20Compatibilization%20in%20Ternary%20Polymer%20Nanocomposites:%20Comparing%20Theory%20and%20Experiments&rft.jtitle=Macromolecules&rft.au=Maguire,%20Shawn%20M&rft.aucorp=Univ.%20of%20Delaware,%20Newark,%20DE%20(United%20States)&rft.date=2021-01-26&rft.volume=54&rft.issue=2&rft.spage=797&rft.epage=811&rft.pages=797-811&rft.issn=0024-9297&rft.eissn=1520-5835&rft_id=info:doi/10.1021/acs.macromol.0c02345&rft_dat=%3Cacs_osti_%3Ei32538192%3C/acs_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |