Rapid Electrochemical Methane Functionalization Involves Pd–Pd Bonded Intermediates

High-valent Pd complexes are potent agents for the oxidative functionalization of inert C–H bonds, and it was previously shown that rapid electrocatalytic methane monofunctionalization could be achieved by electro-oxidation of PdII to a critical dinuclear PdIII intermediate in concentrated or fuming...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-12, Vol.142 (49), p.20631-20639
Hauptverfasser:	Kim, R. Soyoung, Wegener, Evan C, Yang, Min Chieh, O’Reilly, Matthew E, Oh, Seokjoon, Hendon, Christopher H, Miller, Jeffrey T, Surendranath, Yogesh
Format:	Artikel
Sprache:	eng
Schlagworte:	INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Online-Zugang:	Volltext
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