Proton-Coupled Group Transfer Enables Concerted Protonation Pathways Relevant to Small-Molecule Activation

The mechanistic identification of Nature’s use of concerted reactions, in which all bond breaking and bond making occurs in a single step, has inspired rational designs for artificial synthetic transformations via pathways that bypass high-energy intermediates that would otherwise be thermodynamical...

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Veröffentlicht in:Inorganic chemistry 2021-11, Vol.60 (22), p.16953-16965
Hauptverfasser: Sampaio, Renato N, DiMarco, Brian N, Concepcion, Javier J
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Sprache:eng
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