Intermediate Yb valence in the Zintl phases Yb14MSb11(M=Zn,Mn,Mg): XANES, magnetism, and heat capacity

Yb14MnSb11 is a magnetic Zintl compound as well as being one of the best high temperature p -type thermoelectric materials. According to the Zintl formalism, which defines intermetallic phases where cations and anions are valence satisfied, this structure type is nominally made up of 14 Yb2+ , 1 MnS...

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Veröffentlicht in:Physical review materials 2020-11, Vol.4 (11)
Hauptverfasser: He, Allan, Wille, Elizabeth L. Kunz, Moreau, Liane M., Thomas, Sean M., Lawrence, Jon M., Bauer, Eric D., Booth, Corwin H., Kauzlarich, Susan M.
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Sprache:eng
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