Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution
Using neutron powder diffraction and magnetic susceptibility measurements, we report on the preparation and characterization of the temperature- and field-dependent properties of CaY2ZrFe4O12, a composition closely related to the high-temperature ferrimagnet Y3Fe5O12. By diluting the concentration o...
Gespeichert in:
| Veröffentlicht in: | Inorganic chemistry 2021-05, Vol.60 (9), p.6249-6254 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 6254 |
|---|---|
| container_issue | 9 |
| container_start_page | 6249 |
| container_title | Inorganic chemistry |
| container_volume | 60 |
| creator | Milam-Guerrero, JoAnna Zheng, Michelle Spence, Nicole R Calder, Stuart Lapidus, Saul Melot, Brent C |
| description | Using neutron powder diffraction and magnetic susceptibility measurements, we report on the preparation and characterization of the temperature- and field-dependent properties of CaY2ZrFe4O12, a composition closely related to the high-temperature ferrimagnet Y3Fe5O12. By diluting the concentration of paramagnetic ions on the octahedral sublattice of the garnet structure, we find temperature-dependent canting of the magnetic moments. This reflects the importance of the octahedral sublattice in mediating the magnetic interactions between the tetrahedral sites and offers insight into a large number of competing magnetic interactions in the garnet structure. |
| doi_str_mv | 10.1021/acs.inorgchem.0c03809 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_1820767</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2516224248</sourcerecordid><originalsourceid>FETCH-LOGICAL-a373t-8eaeb98839d8db9d8872cd108213976f11b5d0c4c2874670a6c1562ca268cdca3</originalsourceid><addsrcrecordid>eNqFkUFvGyEQhVHVqHHT_oRWqKde7AywC-yxcts0UiJLSSr1hthZbBN5wQVWag_978W1k2svDAzfeyN4hLxjsGDA2aXFvPAhpg1u3bgABKGhe0FmrOUwbxn8eElmAHXPpOzOyeucHwGgE418Rc6F0Epp4DPyZ2lD8WFD45qWraO3dhNc8Uhv4-hCyTSGf_0VFrt1Q7I7eu-LO-A20OtUr1e__ODolU1VSH2gdy7vY8iOlkg_ezs-OS5t8RW_n_pcfJkOhzfkbG132b091Qvy_euXh-W3-c3q6nr56WZuhRJlrp11fae16AY99HXRiuPAQHMmOiXXjPXtANgg16qRCqxE1kqOlkuNA1pxQT4cfWMdbTLWF-AWYwgOi2Gag5KqQh-P0D7Fn5PLxYw-o9vtbHBxyoa3THLe8EZXtD2imGLOya3NPvnRpt-GgTnEY2o85jkec4qn6t6fRkz96IZn1VMeFWBH4KB_jFMK9Vv-Y_oX1Y6gZg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2516224248</pqid></control><display><type>article</type><title>Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution</title><source>ACS Publications</source><creator>Milam-Guerrero, JoAnna ; Zheng, Michelle ; Spence, Nicole R ; Calder, Stuart ; Lapidus, Saul ; Melot, Brent C</creator><creatorcontrib>Milam-Guerrero, JoAnna ; Zheng, Michelle ; Spence, Nicole R ; Calder, Stuart ; Lapidus, Saul ; Melot, Brent C ; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)</creatorcontrib><description>Using neutron powder diffraction and magnetic susceptibility measurements, we report on the preparation and characterization of the temperature- and field-dependent properties of CaY2ZrFe4O12, a composition closely related to the high-temperature ferrimagnet Y3Fe5O12. By diluting the concentration of paramagnetic ions on the octahedral sublattice of the garnet structure, we find temperature-dependent canting of the magnetic moments. This reflects the importance of the octahedral sublattice in mediating the magnetic interactions between the tetrahedral sites and offers insight into a large number of competing magnetic interactions in the garnet structure.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.0c03809</identifier><identifier>PMID: 33877802</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Chemical structure ; Granular materials ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; Magnetic properties ; Order ; Quantum mechanics</subject><ispartof>Inorganic chemistry, 2021-05, Vol.60 (9), p.6249-6254</ispartof><rights>2021 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-a373t-8eaeb98839d8db9d8872cd108213976f11b5d0c4c2874670a6c1562ca268cdca3</cites><orcidid>0000-0002-7486-4325 ; 0000-0002-7078-8206 ; 0000000184023741 ; 0000000274864325 ; 0000000270788206 ; 0000000215330251</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.0c03809$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03809$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33877802$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1820767$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Milam-Guerrero, JoAnna</creatorcontrib><creatorcontrib>Zheng, Michelle</creatorcontrib><creatorcontrib>Spence, Nicole R</creatorcontrib><creatorcontrib>Calder, Stuart</creatorcontrib><creatorcontrib>Lapidus, Saul</creatorcontrib><creatorcontrib>Melot, Brent C</creatorcontrib><creatorcontrib>Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)</creatorcontrib><title>Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>Using neutron powder diffraction and magnetic susceptibility measurements, we report on the preparation and characterization of the temperature- and field-dependent properties of CaY2ZrFe4O12, a composition closely related to the high-temperature ferrimagnet Y3Fe5O12. By diluting the concentration of paramagnetic ions on the octahedral sublattice of the garnet structure, we find temperature-dependent canting of the magnetic moments. This reflects the importance of the octahedral sublattice in mediating the magnetic interactions between the tetrahedral sites and offers insight into a large number of competing magnetic interactions in the garnet structure.</description><subject>Chemical structure</subject><subject>Granular materials</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>Magnetic properties</subject><subject>Order</subject><subject>Quantum mechanics</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkUFvGyEQhVHVqHHT_oRWqKde7AywC-yxcts0UiJLSSr1hthZbBN5wQVWag_978W1k2svDAzfeyN4hLxjsGDA2aXFvPAhpg1u3bgABKGhe0FmrOUwbxn8eElmAHXPpOzOyeucHwGgE418Rc6F0Epp4DPyZ2lD8WFD45qWraO3dhNc8Uhv4-hCyTSGf_0VFrt1Q7I7eu-LO-A20OtUr1e__ODolU1VSH2gdy7vY8iOlkg_ezs-OS5t8RW_n_pcfJkOhzfkbG132b091Qvy_euXh-W3-c3q6nr56WZuhRJlrp11fae16AY99HXRiuPAQHMmOiXXjPXtANgg16qRCqxE1kqOlkuNA1pxQT4cfWMdbTLWF-AWYwgOi2Gag5KqQh-P0D7Fn5PLxYw-o9vtbHBxyoa3THLe8EZXtD2imGLOya3NPvnRpt-GgTnEY2o85jkec4qn6t6fRkz96IZn1VMeFWBH4KB_jFMK9Vv-Y_oX1Y6gZg</recordid><startdate>20210503</startdate><enddate>20210503</enddate><creator>Milam-Guerrero, JoAnna</creator><creator>Zheng, Michelle</creator><creator>Spence, Nicole R</creator><creator>Calder, Stuart</creator><creator>Lapidus, Saul</creator><creator>Melot, Brent C</creator><general>American Chemical Society</general><general>American Chemical Society (ACS)</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-7486-4325</orcidid><orcidid>https://orcid.org/0000-0002-7078-8206</orcidid><orcidid>https://orcid.org/0000000184023741</orcidid><orcidid>https://orcid.org/0000000274864325</orcidid><orcidid>https://orcid.org/0000000270788206</orcidid><orcidid>https://orcid.org/0000000215330251</orcidid></search><sort><creationdate>20210503</creationdate><title>Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution</title><author>Milam-Guerrero, JoAnna ; Zheng, Michelle ; Spence, Nicole R ; Calder, Stuart ; Lapidus, Saul ; Melot, Brent C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a373t-8eaeb98839d8db9d8872cd108213976f11b5d0c4c2874670a6c1562ca268cdca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical structure</topic><topic>Granular materials</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>Magnetic properties</topic><topic>Order</topic><topic>Quantum mechanics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Milam-Guerrero, JoAnna</creatorcontrib><creatorcontrib>Zheng, Michelle</creatorcontrib><creatorcontrib>Spence, Nicole R</creatorcontrib><creatorcontrib>Calder, Stuart</creatorcontrib><creatorcontrib>Lapidus, Saul</creatorcontrib><creatorcontrib>Melot, Brent C</creatorcontrib><creatorcontrib>Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Milam-Guerrero, JoAnna</au><au>Zheng, Michelle</au><au>Spence, Nicole R</au><au>Calder, Stuart</au><au>Lapidus, Saul</au><au>Melot, Brent C</au><aucorp>Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2021-05-03</date><risdate>2021</risdate><volume>60</volume><issue>9</issue><spage>6249</spage><epage>6254</epage><pages>6249-6254</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Using neutron powder diffraction and magnetic susceptibility measurements, we report on the preparation and characterization of the temperature- and field-dependent properties of CaY2ZrFe4O12, a composition closely related to the high-temperature ferrimagnet Y3Fe5O12. By diluting the concentration of paramagnetic ions on the octahedral sublattice of the garnet structure, we find temperature-dependent canting of the magnetic moments. This reflects the importance of the octahedral sublattice in mediating the magnetic interactions between the tetrahedral sites and offers insight into a large number of competing magnetic interactions in the garnet structure.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>33877802</pmid><doi>10.1021/acs.inorgchem.0c03809</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-7486-4325</orcidid><orcidid>https://orcid.org/0000-0002-7078-8206</orcidid><orcidid>https://orcid.org/0000000184023741</orcidid><orcidid>https://orcid.org/0000000274864325</orcidid><orcidid>https://orcid.org/0000000270788206</orcidid><orcidid>https://orcid.org/0000000215330251</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0020-1669 |
| ispartof | Inorganic chemistry, 2021-05, Vol.60 (9), p.6249-6254 |
| issn | 0020-1669 1520-510X |
| language | eng |
| recordid | cdi_osti_scitechconnect_1820767 |
| source | ACS Publications |
| subjects | Chemical structure Granular materials INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Magnetic properties Order Quantum mechanics |
| title | Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T02%3A09%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Canting%20of%20the%20Magnetic%20Moments%20on%20the%20Octahedral%20Site%20of%20an%20Iron%20Oxide%20Garnet%20in%20Response%20to%20Diamagnetic%20Cation%20Substitution&rft.jtitle=Inorganic%20chemistry&rft.au=Milam-Guerrero,%20JoAnna&rft.aucorp=Oak%20Ridge%20National%20Lab.%20(ORNL),%20Oak%20Ridge,%20TN%20(United%20States)&rft.date=2021-05-03&rft.volume=60&rft.issue=9&rft.spage=6249&rft.epage=6254&rft.pages=6249-6254&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.0c03809&rft_dat=%3Cproquest_osti_%3E2516224248%3C/proquest_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2516224248&rft_id=info:pmid/33877802&rfr_iscdi=true |