Defying Thermodynamics: Stabilization of Alane Within Covalent Triazine Frameworks for Reversible Hydrogen Storage

The highly unfavorable thermodynamics of direct aluminum hydrogenation can be overcome by stabilizing alane within a nanoporous bipyridine‐functionalized covalent triazine framework (AlH3@CTF‐bipyridine). This material and the counterpart AlH3@CTF‐biphenyl rapidly desorb H2 between 95 and 154 °C, wi...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2021-12, Vol.60 (49), p.25815-25824
Hauptverfasser:	Stavila, Vitalie, Li, Sichi, Dun, Chaochao, Marple, Maxwell A. T., Mason, Harris E., Snider, Jonathan L., Reynolds, Joseph E., El Gabaly, Farid, Sugar, Joshua D., Spataru, Catalin D., Zhou, Xiaowang, Dizdar, Brennan, Majzoub, Eric H., Chatterjee, Ruchira, Yano, Junko, Schlomberg, Hendrik, Lotsch, Bettina V., Urban, Jeffrey J., Wood, Brandon C., Allendorf, Mark D.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Aluminum hydrides Computer applications Coordination Chemistry Covalent Triazine Frameworks Dehydrogenation Electron transfer Hydrides Hydrogen Storage MATERIALS SCIENCE Metal hydrides Nanoconfinement NMR NMR spectroscopy Nuclear magnetic resonance Spectroscopy Thermochemistry Thermodynamics Triazine
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!