The Molybdenum(V) and Tungsten(VI) Oxoazides [MoO(N3)3], [MoO(N3)3⋅2 CH3CN], [(bipy)MoO(N3)3], [MoO(N3)5]2−, [WO(N3)4], and [WO(N3)4⋅CH3CN]
A series of novel molybdenum(V) and tungsten(VI) oxoazides was prepared starting from [MOF4] (M=Mo, W) and Me3SiN3. While [WO(N3)4] was formed through fluoride–azide exchange in the reaction of Me3SiN3 with WOF4 in SO2 solution, the reaction with MoOF4 resulted in a reduction of MoVI to MoV and form...
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| creator | Haiges, Ralf Skotnitzki, Juri Fang, Zongtang Dixon, David A. Christe, Karl O. |
| description | A series of novel molybdenum(V) and tungsten(VI) oxoazides was prepared starting from [MOF4] (M=Mo, W) and Me3SiN3. While [WO(N3)4] was formed through fluoride–azide exchange in the reaction of Me3SiN3 with WOF4 in SO2 solution, the reaction with MoOF4 resulted in a reduction of MoVI to MoV and formation of [MoO(N3)3]. Carried out in acetonitrile solution, these reactions resulted in the isolation of the corresponding adducts [MoO(N3)3⋅2 CH3CN] and [WO(N3)4⋅CH3CN]. Subsequent reactions of [MoO(N3)3] with 2,2′‐bipyridine and [PPh4][N3] resulted in the formation and isolation of [(bipy)MoO(N3)3] and [PPh4]2[MoO(N3)5], respectively. Most molybdenum(V) and tungsten(VI) oxoazides were fully characterized by their vibrational spectra, impact, friction and thermal sensitivity data and, in the case of [WO(N3)4⋅CH3CN], [(bipy)MoO(N3)3], and [PPh4]2[MoO(N3)5], by their X‐ray crystal structures.
Mo and W make an impact: A series of novel molybdenum(V) and tungsten(VI) oxoazides were obtained and characterized. [MoO(N3)3] and [WO(N3)4] were obtained by fluoride–azide exchange from [MOF4] and Me3SiN3 as very friction‐ and impact‐sensitive solids. With CH3CN, [MoO(N3)3] and [WO(N3)4] form stable acetonitrile adducts. The reactions of [MoO(N3)3] with 2,2′‐bipyridine and N3− afforded [(bipy)MoO(N3)3] and [MoO(N3)5]2−, respectively. |
| doi_str_mv | 10.1002/anie.201505418 |
| format | Article |
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Mo and W make an impact: A series of novel molybdenum(V) and tungsten(VI) oxoazides were obtained and characterized. [MoO(N3)3] and [WO(N3)4] were obtained by fluoride–azide exchange from [MOF4] and Me3SiN3 as very friction‐ and impact‐sensitive solids. With CH3CN, [MoO(N3)3] and [WO(N3)4] form stable acetonitrile adducts. The reactions of [MoO(N3)3] with 2,2′‐bipyridine and N3− afforded [(bipy)MoO(N3)3] and [MoO(N3)5]2−, respectively.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201505418</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Acetonitrile ; Adducts ; Crystal structure ; crystal structures ; Fluorides ; Molybdenum ; oxoazides ; polyazides ; Sulfur dioxide ; Tungsten ; Vibrational spectra</subject><ispartof>Angewandte Chemie (International ed.), 2015-12, Vol.54 (51), p.15550-15555</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright Wiley Subscription Services, Inc. Dec 2015</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4178-53db8b3c49288c46fbdb46dec1693bab0abf9724fbf4bd7b17a093efb295e56b3</citedby><cites>FETCH-LOGICAL-c4178-53db8b3c49288c46fbdb46dec1693bab0abf9724fbf4bd7b17a093efb295e56b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201505418$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201505418$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/1813887$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Haiges, Ralf</creatorcontrib><creatorcontrib>Skotnitzki, Juri</creatorcontrib><creatorcontrib>Fang, Zongtang</creatorcontrib><creatorcontrib>Dixon, David A.</creatorcontrib><creatorcontrib>Christe, Karl O.</creatorcontrib><title>The Molybdenum(V) and Tungsten(VI) Oxoazides [MoO(N3)3], [MoO(N3)3⋅2 CH3CN], [(bipy)MoO(N3)3], [MoO(N3)5]2−, [WO(N3)4], and [WO(N3)4⋅CH3CN]</title><title>Angewandte Chemie (International ed.)</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>A series of novel molybdenum(V) and tungsten(VI) oxoazides was prepared starting from [MOF4] (M=Mo, W) and Me3SiN3. While [WO(N3)4] was formed through fluoride–azide exchange in the reaction of Me3SiN3 with WOF4 in SO2 solution, the reaction with MoOF4 resulted in a reduction of MoVI to MoV and formation of [MoO(N3)3]. Carried out in acetonitrile solution, these reactions resulted in the isolation of the corresponding adducts [MoO(N3)3⋅2 CH3CN] and [WO(N3)4⋅CH3CN]. Subsequent reactions of [MoO(N3)3] with 2,2′‐bipyridine and [PPh4][N3] resulted in the formation and isolation of [(bipy)MoO(N3)3] and [PPh4]2[MoO(N3)5], respectively. Most molybdenum(V) and tungsten(VI) oxoazides were fully characterized by their vibrational spectra, impact, friction and thermal sensitivity data and, in the case of [WO(N3)4⋅CH3CN], [(bipy)MoO(N3)3], and [PPh4]2[MoO(N3)5], by their X‐ray crystal structures.
Mo and W make an impact: A series of novel molybdenum(V) and tungsten(VI) oxoazides were obtained and characterized. [MoO(N3)3] and [WO(N3)4] were obtained by fluoride–azide exchange from [MOF4] and Me3SiN3 as very friction‐ and impact‐sensitive solids. With CH3CN, [MoO(N3)3] and [WO(N3)4] form stable acetonitrile adducts. The reactions of [MoO(N3)3] with 2,2′‐bipyridine and N3− afforded [(bipy)MoO(N3)3] and [MoO(N3)5]2−, respectively.</description><subject>Acetonitrile</subject><subject>Adducts</subject><subject>Crystal structure</subject><subject>crystal structures</subject><subject>Fluorides</subject><subject>Molybdenum</subject><subject>oxoazides</subject><subject>polyazides</subject><subject>Sulfur dioxide</subject><subject>Tungsten</subject><subject>Vibrational spectra</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkcFv0zAYxS0EEqPjyjmCSyuRYvuzY-c4VWMt61oOpTugybIdh2V0SRenYuXEBQm02_gP-5fgEBgcEJz8Pfv3nm09hJ4QPCQY0xe6LNyQYsIxZ0TeQ3uEUxKDEHA_zAwgFpKTh-iR9xeBlxIne-jb4txFJ9VqazJXbi77y0GkyyxabMp3vnFlfzkZRPPrSn8sMuejtyfVvD-DAZw9_z3vbj7T3aevozGMZu1-3xTr7eAvJD-juy-3QZ_-kCwctXf9kiGny9hHD3K98u7xz7WH3rw8XIzG8XR-NBkdTGPLiJAxh8xIA5al4S-WJbnJDEsyZ0mSgtEGa5OngrLc5MxkwhChcQouNzTljicGeuhpl1v5plDeFo2z57YqS2cbRSQBKUWAnnXQuq6uNs436qLa1GV4l6I8oQQEMP4vigguCOZtAT007ChbV97XLlfrurjU9VYRrNoOVduhuuswGNLO8KFYue1_aHUwmxz-6Y07bxGKvL7z6vq9SgQIrk5nR2oql4tX42OmXsN3Q9GqFA</recordid><startdate>20151214</startdate><enddate>20151214</enddate><creator>Haiges, Ralf</creator><creator>Skotnitzki, Juri</creator><creator>Fang, Zongtang</creator><creator>Dixon, David A.</creator><creator>Christe, Karl O.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><general>Wiley Blackwell (John Wiley & Sons)</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>OTOTI</scope></search><sort><creationdate>20151214</creationdate><title>The Molybdenum(V) and Tungsten(VI) Oxoazides [MoO(N3)3], [MoO(N3)3⋅2 CH3CN], [(bipy)MoO(N3)3], [MoO(N3)5]2−, [WO(N3)4], and [WO(N3)4⋅CH3CN]</title><author>Haiges, Ralf ; Skotnitzki, Juri ; Fang, Zongtang ; Dixon, David A. ; Christe, Karl O.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4178-53db8b3c49288c46fbdb46dec1693bab0abf9724fbf4bd7b17a093efb295e56b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Acetonitrile</topic><topic>Adducts</topic><topic>Crystal structure</topic><topic>crystal structures</topic><topic>Fluorides</topic><topic>Molybdenum</topic><topic>oxoazides</topic><topic>polyazides</topic><topic>Sulfur dioxide</topic><topic>Tungsten</topic><topic>Vibrational spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Haiges, Ralf</creatorcontrib><creatorcontrib>Skotnitzki, Juri</creatorcontrib><creatorcontrib>Fang, Zongtang</creatorcontrib><creatorcontrib>Dixon, David A.</creatorcontrib><creatorcontrib>Christe, Karl O.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>OSTI.GOV</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Haiges, Ralf</au><au>Skotnitzki, Juri</au><au>Fang, Zongtang</au><au>Dixon, David A.</au><au>Christe, Karl O.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Molybdenum(V) and Tungsten(VI) Oxoazides [MoO(N3)3], [MoO(N3)3⋅2 CH3CN], [(bipy)MoO(N3)3], [MoO(N3)5]2−, [WO(N3)4], and [WO(N3)4⋅CH3CN]</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2015-12-14</date><risdate>2015</risdate><volume>54</volume><issue>51</issue><spage>15550</spage><epage>15555</epage><pages>15550-15555</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>A series of novel molybdenum(V) and tungsten(VI) oxoazides was prepared starting from [MOF4] (M=Mo, W) and Me3SiN3. While [WO(N3)4] was formed through fluoride–azide exchange in the reaction of Me3SiN3 with WOF4 in SO2 solution, the reaction with MoOF4 resulted in a reduction of MoVI to MoV and formation of [MoO(N3)3]. Carried out in acetonitrile solution, these reactions resulted in the isolation of the corresponding adducts [MoO(N3)3⋅2 CH3CN] and [WO(N3)4⋅CH3CN]. Subsequent reactions of [MoO(N3)3] with 2,2′‐bipyridine and [PPh4][N3] resulted in the formation and isolation of [(bipy)MoO(N3)3] and [PPh4]2[MoO(N3)5], respectively. Most molybdenum(V) and tungsten(VI) oxoazides were fully characterized by their vibrational spectra, impact, friction and thermal sensitivity data and, in the case of [WO(N3)4⋅CH3CN], [(bipy)MoO(N3)3], and [PPh4]2[MoO(N3)5], by their X‐ray crystal structures.
Mo and W make an impact: A series of novel molybdenum(V) and tungsten(VI) oxoazides were obtained and characterized. [MoO(N3)3] and [WO(N3)4] were obtained by fluoride–azide exchange from [MOF4] and Me3SiN3 as very friction‐ and impact‐sensitive solids. With CH3CN, [MoO(N3)3] and [WO(N3)4] form stable acetonitrile adducts. The reactions of [MoO(N3)3] with 2,2′‐bipyridine and N3− afforded [(bipy)MoO(N3)3] and [MoO(N3)5]2−, respectively.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/anie.201505418</doi><tpages>6</tpages><edition>International ed. in English</edition><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2015-12, Vol.54 (51), p.15550-15555 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1813887 |
| source | Wiley Online Library - AutoHoldings Journals |
| subjects | Acetonitrile Adducts Crystal structure crystal structures Fluorides Molybdenum oxoazides polyazides Sulfur dioxide Tungsten Vibrational spectra |
| title | The Molybdenum(V) and Tungsten(VI) Oxoazides [MoO(N3)3], [MoO(N3)3⋅2 CH3CN], [(bipy)MoO(N3)3], [MoO(N3)5]2−, [WO(N3)4], and [WO(N3)4⋅CH3CN] |
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