Accurate vertical ionization energy and work function determinations of liquid water and aqueous solutions

The absolute-scale electronic energetics of liquid water and aqueous solutions, both in the bulk and at associated interfaces, are the central determiners of water-based chemistry. However, such information is generally experimentally inaccessible. Here we demonstrate that a refined implementation o...

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Veröffentlicht in:	Chemical science (Cambridge) 2021-08, Vol.12 (31), p.1558-1582
Hauptverfasser:	Thürmer, Stephan, Malerz, Sebastian, Trinter, Florian, Hergenhahn, Uwe, Lee, Chin, Neumark, Daniel M, Meijer, Gerard, Winter, Bernd, Wilkinson, Iain
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous solutions Chemical potential Chemistry Condensed matter physics Electronic structure Fermi level INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Ionization Liquid phases Microjets Perturbation Photoelectrons Referencing Water Work functions
Online-Zugang:	Volltext
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