Strong-field ionization of water. II. Electronic and nuclear dynamics en route to double ionization

In this work, we investigate the role of nuclear motion and strong-field-induced electronic couplings during the double ionization of deuterated water using momentum-resolved coincidence spectroscopy. By examining the three-body dicationic dissociation channel, D+/D+/O, for both few- and multicycle...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Physical review. A 2021-08, Vol.104 (2), Article 023108
Hauptverfasser: Cheng, Chuan, Streeter, Zachary L., Howard, Andrew J., Spanner, Michael, Lucchese, Robert R., McCurdy, C. William, Weinacht, Thomas, Bucksbaum, Philip H., Forbes, Ruaridh
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue 2
container_start_page
container_title Physical review. A
container_volume 104
creator Cheng, Chuan
Streeter, Zachary L.
Howard, Andrew J.
Spanner, Michael
Lucchese, Robert R.
McCurdy, C. William
Weinacht, Thomas
Bucksbaum, Philip H.
Forbes, Ruaridh
description In this work, we investigate the role of nuclear motion and strong-field-induced electronic couplings during the double ionization of deuterated water using momentum-resolved coincidence spectroscopy. By examining the three-body dicationic dissociation channel, D+/D+/O, for both few- and multicycle laser pulses, strong evidence for intrapulse dynamics is observed. The extracted angle- and energy-resolved double ionization yields are compared to classical trajectory simulations of the dissociation dynamics occurring from different electronic states of the dication. In contrast to measurements of single-photon double ionization, pronounced departure from the expectations for vertical ionization is observed, even for pulses as short as 10 fs in duration. We outline numerous mechanisms by which the strong laser field can modify the nuclear wave function en route to final states of the dication where molecular fragmentation occurs. Specifically, we consider the possibility of a coordinate dependence on the strong-field ionization rate, intermediate nuclear motion in monocation states prior to double ionization, and near-resonant laser-induced dipole couplings in the ion. These results highlight the fact that, for small and light molecules such as D2O, a vertical-transition treatment of the ionization dynamics is not sufficient to reproduce the features seen experimentally in the strong-field coincidence double-ionization data.
doi_str_mv 10.1103/PhysRevA.104.023108
format Article
fullrecord <record><control><sourceid>crossref_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_1807494</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1103_PhysRevA_104_023108</sourcerecordid><originalsourceid>FETCH-LOGICAL-c321t-cb723de20ddeb1da683623fc83f12dbe7dd20bad5ff65c48d22ab6bed75c6e503</originalsourceid><addsrcrecordid>eNpNkEtLAzEUhYMoWGp_gZvgfsa8JjOzLKVqoaD4WA-Z5MZGpokkqVJ_vVOq4uocLh-Hy4fQJSUlpYRfP2z26RE-5iUloiSMU9KcoAkTsi3alovTv87kOZql9EYIoVXbSi4nSD_lGPxrYR0MBrvg3ZfKY-Bg8afKEEu8WpV4OYA-gE5j5Q32Oz2Aitjsvdo6nTB4HMMuA84Bm7DrB_i3dYHOrBoSzH5yil5uls-Lu2J9f7tazNeF5ozmQvc14wYYMQZ6apRsuGTc6oZbykwPtTGM9MpU1spKi8YwpnrZg6krLaEifIqujrshZdcl7TLojQ7ej793tCG1aMUI8SOkY0gpgu3eo9uquO8o6Q4-u1-f40F0R5_8G_tAbII</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Strong-field ionization of water. II. Electronic and nuclear dynamics en route to double ionization</title><source>American Physical Society Journals</source><creator>Cheng, Chuan ; Streeter, Zachary L. ; Howard, Andrew J. ; Spanner, Michael ; Lucchese, Robert R. ; McCurdy, C. William ; Weinacht, Thomas ; Bucksbaum, Philip H. ; Forbes, Ruaridh</creator><creatorcontrib>Cheng, Chuan ; Streeter, Zachary L. ; Howard, Andrew J. ; Spanner, Michael ; Lucchese, Robert R. ; McCurdy, C. William ; Weinacht, Thomas ; Bucksbaum, Philip H. ; Forbes, Ruaridh ; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)</creatorcontrib><description>In this work, we investigate the role of nuclear motion and strong-field-induced electronic couplings during the double ionization of deuterated water using momentum-resolved coincidence spectroscopy. By examining the three-body dicationic dissociation channel, D+/D+/O, for both few- and multicycle laser pulses, strong evidence for intrapulse dynamics is observed. The extracted angle- and energy-resolved double ionization yields are compared to classical trajectory simulations of the dissociation dynamics occurring from different electronic states of the dication. In contrast to measurements of single-photon double ionization, pronounced departure from the expectations for vertical ionization is observed, even for pulses as short as 10 fs in duration. We outline numerous mechanisms by which the strong laser field can modify the nuclear wave function en route to final states of the dication where molecular fragmentation occurs. Specifically, we consider the possibility of a coordinate dependence on the strong-field ionization rate, intermediate nuclear motion in monocation states prior to double ionization, and near-resonant laser-induced dipole couplings in the ion. These results highlight the fact that, for small and light molecules such as D2O, a vertical-transition treatment of the ionization dynamics is not sufficient to reproduce the features seen experimentally in the strong-field coincidence double-ionization data.</description><identifier>ISSN: 2469-9926</identifier><identifier>EISSN: 2469-9934</identifier><identifier>DOI: 10.1103/PhysRevA.104.023108</identifier><language>eng</language><publisher>United States</publisher><subject>NUCLEAR PHYSICS AND RADIATION PHYSICS</subject><ispartof>Physical review. A, 2021-08, Vol.104 (2), Article 023108</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-cb723de20ddeb1da683623fc83f12dbe7dd20bad5ff65c48d22ab6bed75c6e503</citedby><cites>FETCH-LOGICAL-c321t-cb723de20ddeb1da683623fc83f12dbe7dd20bad5ff65c48d22ab6bed75c6e503</cites><orcidid>0000-0003-0303-3222 ; 0000-0003-2097-5991 ; 0000-0002-8094-7047</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,2876,2877,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1807494$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Cheng, Chuan</creatorcontrib><creatorcontrib>Streeter, Zachary L.</creatorcontrib><creatorcontrib>Howard, Andrew J.</creatorcontrib><creatorcontrib>Spanner, Michael</creatorcontrib><creatorcontrib>Lucchese, Robert R.</creatorcontrib><creatorcontrib>McCurdy, C. William</creatorcontrib><creatorcontrib>Weinacht, Thomas</creatorcontrib><creatorcontrib>Bucksbaum, Philip H.</creatorcontrib><creatorcontrib>Forbes, Ruaridh</creatorcontrib><creatorcontrib>Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)</creatorcontrib><title>Strong-field ionization of water. II. Electronic and nuclear dynamics en route to double ionization</title><title>Physical review. A</title><description>In this work, we investigate the role of nuclear motion and strong-field-induced electronic couplings during the double ionization of deuterated water using momentum-resolved coincidence spectroscopy. By examining the three-body dicationic dissociation channel, D+/D+/O, for both few- and multicycle laser pulses, strong evidence for intrapulse dynamics is observed. The extracted angle- and energy-resolved double ionization yields are compared to classical trajectory simulations of the dissociation dynamics occurring from different electronic states of the dication. In contrast to measurements of single-photon double ionization, pronounced departure from the expectations for vertical ionization is observed, even for pulses as short as 10 fs in duration. We outline numerous mechanisms by which the strong laser field can modify the nuclear wave function en route to final states of the dication where molecular fragmentation occurs. Specifically, we consider the possibility of a coordinate dependence on the strong-field ionization rate, intermediate nuclear motion in monocation states prior to double ionization, and near-resonant laser-induced dipole couplings in the ion. These results highlight the fact that, for small and light molecules such as D2O, a vertical-transition treatment of the ionization dynamics is not sufficient to reproduce the features seen experimentally in the strong-field coincidence double-ionization data.</description><subject>NUCLEAR PHYSICS AND RADIATION PHYSICS</subject><issn>2469-9926</issn><issn>2469-9934</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLAzEUhYMoWGp_gZvgfsa8JjOzLKVqoaD4WA-Z5MZGpokkqVJ_vVOq4uocLh-Hy4fQJSUlpYRfP2z26RE-5iUloiSMU9KcoAkTsi3alovTv87kOZql9EYIoVXbSi4nSD_lGPxrYR0MBrvg3ZfKY-Bg8afKEEu8WpV4OYA-gE5j5Q32Oz2Aitjsvdo6nTB4HMMuA84Bm7DrB_i3dYHOrBoSzH5yil5uls-Lu2J9f7tazNeF5ozmQvc14wYYMQZ6apRsuGTc6oZbykwPtTGM9MpU1spKi8YwpnrZg6krLaEifIqujrshZdcl7TLojQ7ej793tCG1aMUI8SOkY0gpgu3eo9uquO8o6Q4-u1-f40F0R5_8G_tAbII</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Cheng, Chuan</creator><creator>Streeter, Zachary L.</creator><creator>Howard, Andrew J.</creator><creator>Spanner, Michael</creator><creator>Lucchese, Robert R.</creator><creator>McCurdy, C. William</creator><creator>Weinacht, Thomas</creator><creator>Bucksbaum, Philip H.</creator><creator>Forbes, Ruaridh</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0003-0303-3222</orcidid><orcidid>https://orcid.org/0000-0003-2097-5991</orcidid><orcidid>https://orcid.org/0000-0002-8094-7047</orcidid></search><sort><creationdate>20210801</creationdate><title>Strong-field ionization of water. II. Electronic and nuclear dynamics en route to double ionization</title><author>Cheng, Chuan ; Streeter, Zachary L. ; Howard, Andrew J. ; Spanner, Michael ; Lucchese, Robert R. ; McCurdy, C. William ; Weinacht, Thomas ; Bucksbaum, Philip H. ; Forbes, Ruaridh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-cb723de20ddeb1da683623fc83f12dbe7dd20bad5ff65c48d22ab6bed75c6e503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>NUCLEAR PHYSICS AND RADIATION PHYSICS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Chuan</creatorcontrib><creatorcontrib>Streeter, Zachary L.</creatorcontrib><creatorcontrib>Howard, Andrew J.</creatorcontrib><creatorcontrib>Spanner, Michael</creatorcontrib><creatorcontrib>Lucchese, Robert R.</creatorcontrib><creatorcontrib>McCurdy, C. William</creatorcontrib><creatorcontrib>Weinacht, Thomas</creatorcontrib><creatorcontrib>Bucksbaum, Philip H.</creatorcontrib><creatorcontrib>Forbes, Ruaridh</creatorcontrib><creatorcontrib>Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Physical review. A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Chuan</au><au>Streeter, Zachary L.</au><au>Howard, Andrew J.</au><au>Spanner, Michael</au><au>Lucchese, Robert R.</au><au>McCurdy, C. William</au><au>Weinacht, Thomas</au><au>Bucksbaum, Philip H.</au><au>Forbes, Ruaridh</au><aucorp>Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Strong-field ionization of water. II. Electronic and nuclear dynamics en route to double ionization</atitle><jtitle>Physical review. A</jtitle><date>2021-08-01</date><risdate>2021</risdate><volume>104</volume><issue>2</issue><artnum>023108</artnum><issn>2469-9926</issn><eissn>2469-9934</eissn><abstract>In this work, we investigate the role of nuclear motion and strong-field-induced electronic couplings during the double ionization of deuterated water using momentum-resolved coincidence spectroscopy. By examining the three-body dicationic dissociation channel, D+/D+/O, for both few- and multicycle laser pulses, strong evidence for intrapulse dynamics is observed. The extracted angle- and energy-resolved double ionization yields are compared to classical trajectory simulations of the dissociation dynamics occurring from different electronic states of the dication. In contrast to measurements of single-photon double ionization, pronounced departure from the expectations for vertical ionization is observed, even for pulses as short as 10 fs in duration. We outline numerous mechanisms by which the strong laser field can modify the nuclear wave function en route to final states of the dication where molecular fragmentation occurs. Specifically, we consider the possibility of a coordinate dependence on the strong-field ionization rate, intermediate nuclear motion in monocation states prior to double ionization, and near-resonant laser-induced dipole couplings in the ion. These results highlight the fact that, for small and light molecules such as D2O, a vertical-transition treatment of the ionization dynamics is not sufficient to reproduce the features seen experimentally in the strong-field coincidence double-ionization data.</abstract><cop>United States</cop><doi>10.1103/PhysRevA.104.023108</doi><orcidid>https://orcid.org/0000-0003-0303-3222</orcidid><orcidid>https://orcid.org/0000-0003-2097-5991</orcidid><orcidid>https://orcid.org/0000-0002-8094-7047</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 2469-9926
ispartof Physical review. A, 2021-08, Vol.104 (2), Article 023108
issn 2469-9926
2469-9934
language eng
recordid cdi_osti_scitechconnect_1807494
source American Physical Society Journals
subjects NUCLEAR PHYSICS AND RADIATION PHYSICS
title Strong-field ionization of water. II. Electronic and nuclear dynamics en route to double ionization
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T04%3A02%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Strong-field%20ionization%20of%20water.%20II.%20Electronic%20and%20nuclear%20dynamics%20en%20route%20to%20double%20ionization&rft.jtitle=Physical%20review.%20A&rft.au=Cheng,%20Chuan&rft.aucorp=Lawrence%20Berkeley%20National%20Lab.%20(LBNL),%20Berkeley,%20CA%20(United%20States)&rft.date=2021-08-01&rft.volume=104&rft.issue=2&rft.artnum=023108&rft.issn=2469-9926&rft.eissn=2469-9934&rft_id=info:doi/10.1103/PhysRevA.104.023108&rft_dat=%3Ccrossref_osti_%3E10_1103_PhysRevA_104_023108%3C/crossref_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true