Concerted proton–electron transfer reactions of manganese–hydroxo and manganese–oxo complexes

The enzymes manganese superoxide dismutase and manganese lipoxygenase use MnIII–hydroxo centres to mediate proton-coupled electron transfer (PCET) reactions with substrate. As manganese is earth-abundant and inexpensive, manganese catalysts are of interest for synthetic applications. Recent years ha...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-06, Vol.56 (65)
Hauptverfasser:	Mayfield, Jaycee R., Grotemeyer, Elizabeth N., Jackson, Timothy A.
Format:	Artikel
Sprache:	eng
Schlagworte:	INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Online-Zugang:	Volltext
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