Dinitrogen Reduction to Ammonium at Rhenium Utilizing Light and Proton-Coupled Electron Transfer

The direct scission of the triple bond of dinitrogen (N2) by a metal complex is an alluring entry point into the transformation of N2 to ammonia (NH3) in molecular catalysis. Reported herein is a pincer-ligated rhenium system that reduces N2 to NH3 via a well-defined reaction sequence involving redu...

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Veröffentlicht in:	Journal of the American Chemical Society 2019-12, Vol.141 (51), p.20198-20208
Hauptverfasser:	Bruch, Quinton J, Connor, Gannon P, Chen, Chun-Hsing, Holland, Patrick L, Mayer, James M, Hasanayn, Faraj, Miller, Alexander J. M
Format:	Artikel
Sprache:	eng
Schlagworte:	crystal cleavage INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ligands molecular structure nitrides redox reactions
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