Metal–Organic Frameworks against Toxic Chemicals
Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly....
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| Veröffentlicht in: | Chemical reviews 2020-08, Vol.120 (16), p.8130-8160 |
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| creator | Islamoglu, Timur Chen, Zhijie Wasson, Megan C Buru, Cassandra T Kirlikovali, Kent O Afrin, Unjila Mian, Mohammad Rasel Farha, Omar K |
| description | Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal–organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO. |
| doi_str_mv | 10.1021/acs.chemrev.9b00828 |
| format | Article |
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This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.</description><identifier>ISSN: 0009-2665</identifier><identifier>EISSN: 1520-6890</identifier><identifier>DOI: 10.1021/acs.chemrev.9b00828</identifier><identifier>PMID: 32207607</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Adsorbents ; Ammonia ; Blistering ; Cations ; Chemical warfare ; Chemicals ; Chemistry ; Hydrogen sulfide ; Metal-organic frameworks ; Nitrogen dioxide ; Self-assembly ; Sulfur dioxide</subject><ispartof>Chemical reviews, 2020-08, Vol.120 (16), p.8130-8160</ispartof><rights>Copyright American Chemical Society Aug 26, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a466t-f3ece63ca4fbb38b54fbfde3a1d0d7503509571358f4672e31fcb849d34766913</citedby><cites>FETCH-LOGICAL-a466t-f3ece63ca4fbb38b54fbfde3a1d0d7503509571358f4672e31fcb849d34766913</cites><orcidid>0000-0001-8329-1015 ; 0000-0002-9904-9845 ; 0000-0003-3688-9158 ; 0000-0002-9384-2033 ; 0000-0001-6142-8252 ; 0000-0001-9232-7382 ; 0000000293842033 ; 0000000161428252 ; 0000000336889158 ; 0000000192327382 ; 0000000183291015 ; 0000000299049845</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.chemrev.9b00828$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.chemrev.9b00828$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2763,27074,27922,27923,56736,56786</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32207607$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1800554$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Islamoglu, Timur</creatorcontrib><creatorcontrib>Chen, Zhijie</creatorcontrib><creatorcontrib>Wasson, Megan C</creatorcontrib><creatorcontrib>Buru, Cassandra T</creatorcontrib><creatorcontrib>Kirlikovali, Kent O</creatorcontrib><creatorcontrib>Afrin, Unjila</creatorcontrib><creatorcontrib>Mian, Mohammad Rasel</creatorcontrib><creatorcontrib>Farha, Omar K</creatorcontrib><creatorcontrib>Northwestern Univ., Evanston, IL (United States)</creatorcontrib><title>Metal–Organic Frameworks against Toxic Chemicals</title><title>Chemical reviews</title><addtitle>Chem. 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| fulltext | fulltext |
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| ispartof | Chemical reviews, 2020-08, Vol.120 (16), p.8130-8160 |
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| language | eng |
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| source | ACS Publications |
| subjects | Adsorbents Ammonia Blistering Cations Chemical warfare Chemicals Chemistry Hydrogen sulfide Metal-organic frameworks Nitrogen dioxide Self-assembly Sulfur dioxide |
| title | Metal–Organic Frameworks against Toxic Chemicals |
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