Sugar Acetate-based Low Molecular Weight Organogelators

Sugar Acetate-based Low Molecular Weight Organogelators

Two novel organogelators that incorporate sugar acetate segments have been identified. One contains a sugar acetate linked directly to an alkyl group, while the second includes an amide linker. We describe the syntheses of both organogelators, as well as their gelation properties in various hydrocar...

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Veröffentlicht in:Chemistry letters 2020-09, Vol.49 (9), p.1026-1029
Hauptverfasser: Gentry, Brian M., Perry, Robert, Laurie, Tyler, Beckman, Eric J., Enick, Robert M., Keith, John A.
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Chemistry
Density functional theory
Gelation
Low molecular weights
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container_end_page 1029
container_issue 9
container_start_page 1026
container_title Chemistry letters
container_volume 49
creator Gentry, Brian M.
Perry, Robert
Laurie, Tyler
Beckman, Eric J.
Enick, Robert M.
Keith, John A.
description Two novel organogelators that incorporate sugar acetate segments have been identified. One contains a sugar acetate linked directly to an alkyl group, while the second includes an amide linker. We describe the syntheses of both organogelators, as well as their gelation properties in various hydrocarbon liquids. We also use molecular modeling with a generic classical force field and Kohn-Sham density functional theory to provide atomic scale insights and physical justification for gelation mechanisms.
doi_str_mv 10.1246/cl.200333
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source Oxford University Press Journals All Titles (1996-Current)
subjects Chemistry
Density functional theory
Gelation
Low molecular weights
title Sugar Acetate-based Low Molecular Weight Organogelators
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