Unravel unusual hardening behavior of a Pd–Ni–P metallic glass in its supercooled liquid region
Monolithic metallic glasses often exhibit work softening induced by high atom mobility in the supercooled liquid region in tension. In this work, we report an unusual viscous flow of the Pd42.5Ni42.5P15 metallic glass in its supercooled liquid region, which is characterized by a remarkable hardening...
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| Veröffentlicht in: | Applied physics letters 2021-03, Vol.118 (12) |
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| container_title | Applied physics letters |
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| creator | Cao, Y. H. Du, Q. Liu, X. J. Wang, L. Wu, Y. Wang, H. Jiang, S. H. Ren, Y. Nieh, T. G. Lu, Z. P. |
| description | Monolithic metallic glasses often exhibit work softening induced by high atom mobility in the supercooled liquid region in tension. In this work, we report an unusual viscous flow of the Pd42.5Ni42.5P15 metallic glass in its supercooled liquid region, which is characterized by a remarkable hardening behavior with decent plasticity during tension. To unravel the causes of this unusual hardening, we conducted structural and thermodynamic analyses by employing several experiments, including dynamic mechanical analysis, differential scanning calorimetry, high-resolution transmission electron microscopy, and in situ heating synchrotron high-energy x-ray diffraction. It was found that the unusual hardening behavior was attributed to structural ordering during deformation, rather than nanocrystallization or structural relaxation observed, sometimes, in metallic glasses deformed in supercooled liquid region. We also incorporated an additional work hardening region in the modified deformation map for metallic glasses. |
| doi_str_mv | 10.1063/5.0039755 |
| format | Article |
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H. ; Du, Q. ; Liu, X. J. ; Wang, L. ; Wu, Y. ; Wang, H. ; Jiang, S. H. ; Ren, Y. ; Nieh, T. G. ; Lu, Z. P.</creator><creatorcontrib>Cao, Y. H. ; Du, Q. ; Liu, X. J. ; Wang, L. ; Wu, Y. ; Wang, H. ; Jiang, S. H. ; Ren, Y. ; Nieh, T. G. ; Lu, Z. P. ; Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><description>Monolithic metallic glasses often exhibit work softening induced by high atom mobility in the supercooled liquid region in tension. In this work, we report an unusual viscous flow of the Pd42.5Ni42.5P15 metallic glass in its supercooled liquid region, which is characterized by a remarkable hardening behavior with decent plasticity during tension. To unravel the causes of this unusual hardening, we conducted structural and thermodynamic analyses by employing several experiments, including dynamic mechanical analysis, differential scanning calorimetry, high-resolution transmission electron microscopy, and in situ heating synchrotron high-energy x-ray diffraction. It was found that the unusual hardening behavior was attributed to structural ordering during deformation, rather than nanocrystallization or structural relaxation observed, sometimes, in metallic glasses deformed in supercooled liquid region. We also incorporated an additional work hardening region in the modified deformation map for metallic glasses.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/5.0039755</identifier><identifier>CODEN: APPLAB</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Amorphous materials ; Applied physics ; Differential scanning calorimetry ; Dynamic mechanical analysis ; High resolution electron microscopy ; MATERIALS SCIENCE ; Metallic glasses ; Nickel ; Synchrotrons ; Viscous flow ; Work hardening ; Work softening</subject><ispartof>Applied physics letters, 2021-03, Vol.118 (12)</ispartof><rights>Author(s)</rights><rights>2021 Author(s). 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H.</creatorcontrib><creatorcontrib>Du, Q.</creatorcontrib><creatorcontrib>Liu, X. J.</creatorcontrib><creatorcontrib>Wang, L.</creatorcontrib><creatorcontrib>Wu, Y.</creatorcontrib><creatorcontrib>Wang, H.</creatorcontrib><creatorcontrib>Jiang, S. H.</creatorcontrib><creatorcontrib>Ren, Y.</creatorcontrib><creatorcontrib>Nieh, T. G.</creatorcontrib><creatorcontrib>Lu, Z. P.</creatorcontrib><creatorcontrib>Argonne National Lab. (ANL), Argonne, IL (United States)</creatorcontrib><title>Unravel unusual hardening behavior of a Pd–Ni–P metallic glass in its supercooled liquid region</title><title>Applied physics letters</title><description>Monolithic metallic glasses often exhibit work softening induced by high atom mobility in the supercooled liquid region in tension. In this work, we report an unusual viscous flow of the Pd42.5Ni42.5P15 metallic glass in its supercooled liquid region, which is characterized by a remarkable hardening behavior with decent plasticity during tension. To unravel the causes of this unusual hardening, we conducted structural and thermodynamic analyses by employing several experiments, including dynamic mechanical analysis, differential scanning calorimetry, high-resolution transmission electron microscopy, and in situ heating synchrotron high-energy x-ray diffraction. It was found that the unusual hardening behavior was attributed to structural ordering during deformation, rather than nanocrystallization or structural relaxation observed, sometimes, in metallic glasses deformed in supercooled liquid region. We also incorporated an additional work hardening region in the modified deformation map for metallic glasses.</description><subject>Amorphous materials</subject><subject>Applied physics</subject><subject>Differential scanning calorimetry</subject><subject>Dynamic mechanical analysis</subject><subject>High resolution electron microscopy</subject><subject>MATERIALS SCIENCE</subject><subject>Metallic glasses</subject><subject>Nickel</subject><subject>Synchrotrons</subject><subject>Viscous flow</subject><subject>Work hardening</subject><subject>Work softening</subject><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEQx4MoWKsH3yDoSWE12Wz24yjFLyjagz2HbHbSpmyTbbJb8OY7-IY-iVu26EGQgRlm-PGfmT9C55TcUJKyW35DCCsyzg_QiJIsixil-SEakX4cpQWnx-gkhFXf8pixEVJz6-UWatzZLnSyxkvpK7DGLnAJS7k1zmOnscSz6uvj88X0aYbX0Mq6NgovahkCNhabNuDQNeCVczVUuDabzlTYw8I4e4qOtKwDnO3rGM0f7t8mT9H09fF5cjeNFMuLNlI0rvKqzBWUSaY1yUGlmqQakjInQIjOE6kU51wB6FRrlvIq5pRDyWISU8rG6GLQdaE1IijTgloqZy2oVtCs6CPtocsBarzbdBBasXKdt_1dIuYkIVm6c2aMrgZKeReCBy0ab9bSvwtKxM5owcXe6J69HtjdRtn2D__AW-d_QdFU-j_4r_I3Sq-OSw</recordid><startdate>20210322</startdate><enddate>20210322</enddate><creator>Cao, Y. 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P.</au><aucorp>Argonne National Lab. (ANL), Argonne, IL (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unravel unusual hardening behavior of a Pd–Ni–P metallic glass in its supercooled liquid region</atitle><jtitle>Applied physics letters</jtitle><date>2021-03-22</date><risdate>2021</risdate><volume>118</volume><issue>12</issue><issn>0003-6951</issn><eissn>1077-3118</eissn><coden>APPLAB</coden><abstract>Monolithic metallic glasses often exhibit work softening induced by high atom mobility in the supercooled liquid region in tension. In this work, we report an unusual viscous flow of the Pd42.5Ni42.5P15 metallic glass in its supercooled liquid region, which is characterized by a remarkable hardening behavior with decent plasticity during tension. To unravel the causes of this unusual hardening, we conducted structural and thermodynamic analyses by employing several experiments, including dynamic mechanical analysis, differential scanning calorimetry, high-resolution transmission electron microscopy, and in situ heating synchrotron high-energy x-ray diffraction. It was found that the unusual hardening behavior was attributed to structural ordering during deformation, rather than nanocrystallization or structural relaxation observed, sometimes, in metallic glasses deformed in supercooled liquid region. 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| source | AIP Journals Complete; Alma/SFX Local Collection |
| subjects | Amorphous materials Applied physics Differential scanning calorimetry Dynamic mechanical analysis High resolution electron microscopy MATERIALS SCIENCE Metallic glasses Nickel Synchrotrons Viscous flow Work hardening Work softening |
| title | Unravel unusual hardening behavior of a Pd–Ni–P metallic glass in its supercooled liquid region |
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