Controlling Cation‐Cation Interactions in Uranyl Coordination Dimers by Varying the Length of the Dicarboxylate Linker

The chemistry of linear uranyl(V/VI) dioxo cations, [Oyl–U–Oyl]+/2+, is dominated by coordination of uranium in the equatorial plane. Effects of this constraint were evaluated by experiment and theory for gas‐phase mixed‐valence UV/VI coordination dimers in which uranyl moieties are linked by alkyl...

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Veröffentlicht in:	European journal of inorganic chemistry 2020-12, Vol.2020 (47), p.4465-4476
Hauptverfasser:	Maurice, Rémi, Dau, Phuong D., Hodée, Maxime, Renault, Eric, Gibson, John K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations Cation‐cation interaction Chemical Sciences Coordination compounds Coordination dimer Diamonds Dimers Inorganic chemistry Lewis base Molecular structure or physical chemistry Theoretical and Uranium Uranium dioxide Uranyl
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