Leveraging Free Volume Manipulation to Improve the Membrane Separation Performance of Amine‐Functionalized PIM‐1

Gas‐separation polymer membranes display a characteristic permeability–selectivity trade‐off that has limited their industrial use. The most comprehensive approach to improving performance is to devise strategies that simultaneously increase fractional free volume, narrow free volume distribution, a...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2021-03, Vol.60 (12), p.6593-6599
Hauptverfasser:	Mizrahi Rodriguez, Katherine, Lin, Sharon, Wu, Albert X., Han, Gang, Teesdale, Justin J., Doherty, Cara M., Smith, Zachary P.
Format:	Artikel
Sprache:	eng
Schlagworte:	amines Carbon dioxide Crosslinking gas separations Industrial applications Membrane permeability Membrane separation Membranes Microporosity microporous materials Permeability Polymers Selectivity Separation solid-state functionalization Sorption Upper bounds
Online-Zugang:	Volltext
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