The detrimental effect of elemental contaminants when using B additions to improve the creep properties of a Ni-based superalloy

The effect of Si contamination when using B to improve the creep properties of a Ni-based superalloy was investigated using advanced characterization techniques and first-principles simulations on alloys with high and low B levels with varying Si contents. The positive effect of B segregation along...

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Veröffentlicht in:Scripta materialia 2021-08, Vol.201 (C), p.113971, Article 113971
Hauptverfasser: Detrois, Martin, Pei, Zongrui, Liu, Tao, Poplawsky, Jonathan D., Gao, Michael C., Jablonski, Paul D., Hawk, Jeffrey A.
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container_end_page
container_issue C
container_start_page 113971
container_title Scripta materialia
container_volume 201
creator Detrois, Martin
Pei, Zongrui
Liu, Tao
Poplawsky, Jonathan D.
Gao, Michael C.
Jablonski, Paul D.
Hawk, Jeffrey A.
description The effect of Si contamination when using B to improve the creep properties of a Ni-based superalloy was investigated using advanced characterization techniques and first-principles simulations on alloys with high and low B levels with varying Si contents. The positive effect of B segregation along grain boundaries on the creep properties was mitigated by the presence of Si which showed a similar segregation preference. Density functional theory calculations were used for validation by calculating grain boundary cleavage energies. Silicon was shown to decrease grain boundary cohesion which offsets the positive effect of B. [Display omitted]
doi_str_mv 10.1016/j.scriptamat.2021.113971
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subjects Atom-probe tomography
Boron
Creep
Interfaces
Superalloy
title The detrimental effect of elemental contaminants when using B additions to improve the creep properties of a Ni-based superalloy
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