Catalytic C-O bond hydrogenolysis of tetrahydrofuran-dimethanol over metal supported WOx/TiO2 catalysts

[Display omitted] •Pt- & Rh-WOx/TiO2 have 2 orders of magnitude higher activity than Ru- & Pd-WOx/TiO2.•Pt- & Rh-WOx/TiO2 have less overcoats of WOx and more reduction of W6+ to W5+.•THFDM reaction rate passes through a maximum with H2 pressure.•A higher H2 pressure makes H2 coverage hig...

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Veröffentlicht in:	Applied catalysis. B, Environmental Environmental, 2019-12, Vol.258 (C), p.117945, Article 117945
Hauptverfasser:	He, Jiayue, Burt, Samuel P., Ball, Madelyn R., Hermans, Ive, Dumesic, James A., Huber, George W.
Format:	Artikel
Sprache:	eng
Schlagworte:	1,6-hexanediol Biochemicals Biomass Catalyst Catalysts Catalytic activity Chemisorption Continuous flow Conversion Deactivation Hydrogen storage Hydrogenolysis Leaching Metal particles Metals Organic chemistry Oxidation Palladium Platinum Pressure Salts Tetrahydrofuran Titanium dioxide Valence
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