Crystal structure and luminescence properties of lead-free metal halides (C6H5CH2NH3)3MBr6 (M = Bi and Sb)

Organic–inorganic hybrid metal halides have received extensive attention owing to their versatile structures and optoelectronic properties. Herein, we report two lead-free metal halides, (PMA)3BiBr6 and (PMA)3SbBr6 [PMA+: (C6H5CH2NH3)+, as the abbreviation of phenylmethylammonium], which possess iso...

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Veröffentlicht in:	Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2020-01, Vol.8 (22), p.7322-7329
Hauptverfasser:	Chen, Da, Dai, Fulong, Hao, Shiqiang, Zhou, Guojun, Liu, Quanlin, Wolverton, Christopher, Zhao, Jing, Xia, Zhiguo
Format:	Artikel
Sprache:	eng
Schlagworte:	Antimony Bismuth Broadband Crystal structure Crystallography Decomposition Density functional theory Emission Energy gap Excitation spectra Excitons Halides Hydrogen bonding INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Lead free Luminescence Mathematical analysis Metal halides Optical properties Optoelectronics Parameters Photoexcitation Room temperature Steady state Temperature Temperature dependence
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