How Fast Can a Li-Ion Battery Be Charged? Determination of Limiting Fast Charging Conditions

Fast-charge protocols that prevent lithium plating are needed to extend the life span of lithium-ion batteries. Here, we describe a simple experimental method to estimate the minimum charging time below which it is simply impossible to avoid plating at a given temperature. We demonstrate that, by ga...

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Veröffentlicht in:ACS applied energy materials 2021-02, Vol.4 (2), p.1063-1068
Hauptverfasser: F. Rodrigues, Marco T, Son, Seoung-Bum, Colclasure, Andrew M, Shkrob, Ilya A, Trask, Stephen E, Bloom, Ira D, Abraham, Daniel P
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container_end_page 1068
container_issue 2
container_start_page 1063
container_title ACS applied energy materials
container_volume 4
creator F. Rodrigues, Marco T
Son, Seoung-Bum
Colclasure, Andrew M
Shkrob, Ilya A
Trask, Stephen E
Bloom, Ira D
Abraham, Daniel P
description Fast-charge protocols that prevent lithium plating are needed to extend the life span of lithium-ion batteries. Here, we describe a simple experimental method to estimate the minimum charging time below which it is simply impossible to avoid plating at a given temperature. We demonstrate that, by gauging and correcting the ohmic drop that is intrinsic to reference electrodes, the local potential at the anode surface can be reasonably approximated. This finer anode control enables the determination of the maximum average rate at which lithium deposition can be mitigated, establishing realistic boundaries that can inform the development of advanced charging protocols.
doi_str_mv 10.1021/acsaem.0c03114
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source American Chemical Society Journals
subjects ENERGY STORAGE
fast charging
Li-ion battery
lithium plating
raman spectroscopy
reference electrodes
seesaw charging
sensing errors
title How Fast Can a Li-Ion Battery Be Charged? Determination of Limiting Fast Charging Conditions
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