Simplified Method for the In Situ Collection and Laboratory Analysis of Cosmogenic Tracers (Sulfur-35 and Sodium-22) to Determine Residence Time Distributions and Water Ages
The use of cosmogenically produced sulfur-35 (T 1/2 = 87 days) and sodium-22 (T 1/2 = 2.6 years) as intrinsic tracers can provide valuable information on catchment hydrology, flow paths, and subsurface storage. A new and straightforward method was created to determine the activities of both 35S and...
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| Veröffentlicht in: | Analytical chemistry (Washington) 2021-03, Vol.93 (10), p.4472-4478 |
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| creator | Deinhart, Amanda L Bibby, Richard K Visser, Ate Thaw, Melissa Thomas, Keenan |
| description | The use of cosmogenically produced sulfur-35 (T 1/2 = 87 days) and sodium-22 (T 1/2 = 2.6 years) as intrinsic tracers can provide valuable information on catchment hydrology, flow paths, and subsurface storage. A new and straightforward method was created to determine the activities of both 35S and 22Na in various water sources by pumping large volumes (up to 1000 L) of water through cation- and anion-exchange resin columns in the field to collect sodium and sulfate ions and simple chemistry in the lab. Samples are counted for 35S using liquid scintillation counting (LSC) and for 22Na via γ spectroscopy. Our novel in situ method provides faster sample throughput as well as better counting statistics and lower detection limits. Both methods were successfully applied at the Southern Sierra Critical Zone Observatory. |
| doi_str_mv | 10.1021/acs.analchem.0c04490 |
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| source | ACS Publications |
| subjects | Anion exchanging Anions Chemistry Counting Detection limits Flow paths Hydrology INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Organic polymers Potassium Precipitation Scintillation counters Sodium Sodium 22 Spectroscopy Statistical analysis Statistical methods Sulfur Sulfur isotopes Tracers |
| title | Simplified Method for the In Situ Collection and Laboratory Analysis of Cosmogenic Tracers (Sulfur-35 and Sodium-22) to Determine Residence Time Distributions and Water Ages |
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