Identification of LiH and nanocrystalline LiF in the solid–electrolyte interphase of lithium metal anodes
A comprehensive understanding of the solid–electrolyte interphase (SEI) composition is crucial to developing high-energy batteries based on lithium metal anodes. A particularly contentious issue concerns the presence of LiH in the SEI. Here we report on the use of synchrotron-based X-ray diffraction...
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| Veröffentlicht in: | Nature nanotechnology 2021-05, Vol.16 (5), p.549-554 |
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| creator | Shadike, Zulipiya Lee, Hongkyung Borodin, Oleg Cao, Xia Fan, Xiulin Wang, Xuelong Lin, Ruoqian Bak, Seong-Min Ghose, Sanjit Xu, Kang Wang, Chunsheng Liu, Jun Xiao, Jie Yang, Xiao-Qing Hu, Enyuan |
| description | A comprehensive understanding of the solid–electrolyte interphase (SEI) composition is crucial to developing high-energy batteries based on lithium metal anodes. A particularly contentious issue concerns the presence of LiH in the SEI. Here we report on the use of synchrotron-based X-ray diffraction and pair distribution function analysis to identify and differentiate two elusive components, LiH and LiF, in the SEI of lithium metal anodes. LiH is identified as a component of the SEI in high abundance, and the possibility of its misidentification as LiF in the literature is discussed. LiF in the SEI is found to have different structural features from LiF in the bulk phase, including a larger lattice parameter and a smaller grain size ( |
| doi_str_mv | 10.1038/s41565-020-00845-5 |
| format | Article |
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+
transport and explain why an ionic insulator, like LiF, has been found to be a favoured component for the SEI. Finally, pair distribution function analysis reveals key amorphous components in the SEI.
X-ray diffraction and Rietveld refinement analysis confirm the presence of LiH in the solid–electrolyte interphase of lithium metal anodes.</description><identifier>ISSN: 1748-3387</identifier><identifier>EISSN: 1748-3395</identifier><identifier>DOI: 10.1038/s41565-020-00845-5</identifier><identifier>PMID: 33510453</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/299/891 ; 639/638/161/891 ; Anodes ; Batteries ; Chemistry and Materials Science ; Distribution functions ; Electrolytes ; Function analysis ; Grain size ; Interphase ; Lithium ; Lithium fluoride ; lithium metal anode ; MATERIALS SCIENCE ; Metals ; Nanotechnology ; Nanotechnology and Microengineering ; PDF ; synchrotron characterization ; Synchrotrons ; X-ray diffraction</subject><ispartof>Nature nanotechnology, 2021-05, Vol.16 (5), p.549-554</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Limited 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature Limited 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c485t-cbe59fa8dc276e82ac6f114a6696e7160c5879df882dbdce3a157722045189a83</citedby><cites>FETCH-LOGICAL-c485t-cbe59fa8dc276e82ac6f114a6696e7160c5879df882dbdce3a157722045189a83</cites><orcidid>0000-0002-1626-5949 ; 0000-0002-8626-6381 ; 0000-0002-6946-8635 ; 0000-0001-8663-7771 ; 0000-0002-1881-4534 ; 0000-0002-9428-5291 ; 0000-0002-5520-5439 ; 0000-0002-3625-3478 ; 0000000294285291 ; 0000000269468635 ; 0000000236253478 ; 0000000186637771 ; 0000000216265949 ; 0000000255205439 ; 0000000191407495 ; 0000000218814534 ; 0000000286266381</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33510453$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1764002$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Shadike, Zulipiya</creatorcontrib><creatorcontrib>Lee, Hongkyung</creatorcontrib><creatorcontrib>Borodin, Oleg</creatorcontrib><creatorcontrib>Cao, Xia</creatorcontrib><creatorcontrib>Fan, Xiulin</creatorcontrib><creatorcontrib>Wang, Xuelong</creatorcontrib><creatorcontrib>Lin, Ruoqian</creatorcontrib><creatorcontrib>Bak, Seong-Min</creatorcontrib><creatorcontrib>Ghose, Sanjit</creatorcontrib><creatorcontrib>Xu, Kang</creatorcontrib><creatorcontrib>Wang, Chunsheng</creatorcontrib><creatorcontrib>Liu, Jun</creatorcontrib><creatorcontrib>Xiao, Jie</creatorcontrib><creatorcontrib>Yang, Xiao-Qing</creatorcontrib><creatorcontrib>Hu, Enyuan</creatorcontrib><creatorcontrib>Brookhaven National Lab. (BNL), Upton, NY (United States)</creatorcontrib><creatorcontrib>Pacific Northwest National Lab. (PNNL), Richland, WA (United States)</creatorcontrib><title>Identification of LiH and nanocrystalline LiF in the solid–electrolyte interphase of lithium metal anodes</title><title>Nature nanotechnology</title><addtitle>Nat. Nanotechnol</addtitle><addtitle>Nat Nanotechnol</addtitle><description>A comprehensive understanding of the solid–electrolyte interphase (SEI) composition is crucial to developing high-energy batteries based on lithium metal anodes. A particularly contentious issue concerns the presence of LiH in the SEI. Here we report on the use of synchrotron-based X-ray diffraction and pair distribution function analysis to identify and differentiate two elusive components, LiH and LiF, in the SEI of lithium metal anodes. LiH is identified as a component of the SEI in high abundance, and the possibility of its misidentification as LiF in the literature is discussed. LiF in the SEI is found to have different structural features from LiF in the bulk phase, including a larger lattice parameter and a smaller grain size (<3 nm). These characteristics favour Li
+
transport and explain why an ionic insulator, like LiF, has been found to be a favoured component for the SEI. Finally, pair distribution function analysis reveals key amorphous components in the SEI.
X-ray diffraction and Rietveld refinement analysis confirm the presence of LiH in the solid–electrolyte interphase of lithium metal anodes.</description><subject>639/301/299/891</subject><subject>639/638/161/891</subject><subject>Anodes</subject><subject>Batteries</subject><subject>Chemistry and Materials Science</subject><subject>Distribution functions</subject><subject>Electrolytes</subject><subject>Function analysis</subject><subject>Grain size</subject><subject>Interphase</subject><subject>Lithium</subject><subject>Lithium fluoride</subject><subject>lithium metal anode</subject><subject>MATERIALS SCIENCE</subject><subject>Metals</subject><subject>Nanotechnology</subject><subject>Nanotechnology and Microengineering</subject><subject>PDF</subject><subject>synchrotron characterization</subject><subject>Synchrotrons</subject><subject>X-ray diffraction</subject><issn>1748-3387</issn><issn>1748-3395</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kb1uFTEQhVeIiITAC1CgFTRpFvxvb4ki8iNdiSapLV97luvgtS-2t7gd78Ab8iQ42RAkCiqPPN85M6PTdW8w-oARVR8Lw1zwARE0IKQYH_iz7gRLpgZKR_78qVbyuHtZyh1CnIyEveiOKeUYMU5Pum_XDmL1k7em-hT7NPUbf9Wb6PpoYrL5UKoJwUdo_xe9j33dQV9S8O7Xj58QwNacwqFCa1XI-50pcG8SfN35Ze5naPJmlxyUV93RZEKB14_vaXd78fnm_GrYfLm8Pv-0GSxTvA52C3ycjHKWSAGKGCsmjJkRYhQgsUCWKzm6SSnits4CNZhLSUg7CKvRKHravVt9U6leF-sr2J1NMbZlNZaCIUQadLZC-5y-L1Cqnn2xEIKJkJaiCVNUtbFMNvT9P-hdWnJsJ2jCiWBSjHRsFFkpm1MpGSa9z342-aAx0vd56TUv3fLSD3lp3kRvH62X7QzuSfInoAbQFSitFb9C_jv7P7a_AYW1oPs</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Shadike, Zulipiya</creator><creator>Lee, Hongkyung</creator><creator>Borodin, Oleg</creator><creator>Cao, Xia</creator><creator>Fan, Xiulin</creator><creator>Wang, Xuelong</creator><creator>Lin, Ruoqian</creator><creator>Bak, Seong-Min</creator><creator>Ghose, Sanjit</creator><creator>Xu, Kang</creator><creator>Wang, Chunsheng</creator><creator>Liu, Jun</creator><creator>Xiao, Jie</creator><creator>Yang, Xiao-Qing</creator><creator>Hu, Enyuan</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QO</scope><scope>7U5</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>KB.</scope><scope>L6V</scope><scope>L7M</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M7P</scope><scope>M7S</scope><scope>P5Z</scope><scope>P62</scope><scope>P64</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>7X8</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-1626-5949</orcidid><orcidid>https://orcid.org/0000-0002-8626-6381</orcidid><orcidid>https://orcid.org/0000-0002-6946-8635</orcidid><orcidid>https://orcid.org/0000-0001-8663-7771</orcidid><orcidid>https://orcid.org/0000-0002-1881-4534</orcidid><orcidid>https://orcid.org/0000-0002-9428-5291</orcidid><orcidid>https://orcid.org/0000-0002-5520-5439</orcidid><orcidid>https://orcid.org/0000-0002-3625-3478</orcidid><orcidid>https://orcid.org/0000000294285291</orcidid><orcidid>https://orcid.org/0000000269468635</orcidid><orcidid>https://orcid.org/0000000236253478</orcidid><orcidid>https://orcid.org/0000000186637771</orcidid><orcidid>https://orcid.org/0000000216265949</orcidid><orcidid>https://orcid.org/0000000255205439</orcidid><orcidid>https://orcid.org/0000000191407495</orcidid><orcidid>https://orcid.org/0000000218814534</orcidid><orcidid>https://orcid.org/0000000286266381</orcidid></search><sort><creationdate>20210501</creationdate><title>Identification of LiH and nanocrystalline LiF in the solid–electrolyte interphase of lithium metal anodes</title><author>Shadike, Zulipiya ; 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(BNL), Upton, NY (United States)</aucorp><aucorp>Pacific Northwest National Lab. (PNNL), Richland, WA (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Identification of LiH and nanocrystalline LiF in the solid–electrolyte interphase of lithium metal anodes</atitle><jtitle>Nature nanotechnology</jtitle><stitle>Nat. Nanotechnol</stitle><addtitle>Nat Nanotechnol</addtitle><date>2021-05-01</date><risdate>2021</risdate><volume>16</volume><issue>5</issue><spage>549</spage><epage>554</epage><pages>549-554</pages><issn>1748-3387</issn><eissn>1748-3395</eissn><abstract>A comprehensive understanding of the solid–electrolyte interphase (SEI) composition is crucial to developing high-energy batteries based on lithium metal anodes. A particularly contentious issue concerns the presence of LiH in the SEI. Here we report on the use of synchrotron-based X-ray diffraction and pair distribution function analysis to identify and differentiate two elusive components, LiH and LiF, in the SEI of lithium metal anodes. LiH is identified as a component of the SEI in high abundance, and the possibility of its misidentification as LiF in the literature is discussed. LiF in the SEI is found to have different structural features from LiF in the bulk phase, including a larger lattice parameter and a smaller grain size (<3 nm). These characteristics favour Li
+
transport and explain why an ionic insulator, like LiF, has been found to be a favoured component for the SEI. Finally, pair distribution function analysis reveals key amorphous components in the SEI.
X-ray diffraction and Rietveld refinement analysis confirm the presence of LiH in the solid–electrolyte interphase of lithium metal anodes.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>33510453</pmid><doi>10.1038/s41565-020-00845-5</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-1626-5949</orcidid><orcidid>https://orcid.org/0000-0002-8626-6381</orcidid><orcidid>https://orcid.org/0000-0002-6946-8635</orcidid><orcidid>https://orcid.org/0000-0001-8663-7771</orcidid><orcidid>https://orcid.org/0000-0002-1881-4534</orcidid><orcidid>https://orcid.org/0000-0002-9428-5291</orcidid><orcidid>https://orcid.org/0000-0002-5520-5439</orcidid><orcidid>https://orcid.org/0000-0002-3625-3478</orcidid><orcidid>https://orcid.org/0000000294285291</orcidid><orcidid>https://orcid.org/0000000269468635</orcidid><orcidid>https://orcid.org/0000000236253478</orcidid><orcidid>https://orcid.org/0000000186637771</orcidid><orcidid>https://orcid.org/0000000216265949</orcidid><orcidid>https://orcid.org/0000000255205439</orcidid><orcidid>https://orcid.org/0000000191407495</orcidid><orcidid>https://orcid.org/0000000218814534</orcidid><orcidid>https://orcid.org/0000000286266381</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Nature nanotechnology, 2021-05, Vol.16 (5), p.549-554 |
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| source | Nature; Alma/SFX Local Collection |
| subjects | 639/301/299/891 639/638/161/891 Anodes Batteries Chemistry and Materials Science Distribution functions Electrolytes Function analysis Grain size Interphase Lithium Lithium fluoride lithium metal anode MATERIALS SCIENCE Metals Nanotechnology Nanotechnology and Microengineering synchrotron characterization Synchrotrons X-ray diffraction |
| title | Identification of LiH and nanocrystalline LiF in the solid–electrolyte interphase of lithium metal anodes |
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