Reactivity, Formation, and Solubility of Polyoxometalates Probed by Calorimetry

Room temperature calorimetry methods were developed to describe the energy landscapes of six polyoxometalates (POMs), Li–U24, Li–U28, K–U28, Li/K–U60, Mo132, and Mo154, in terms of three components: enthalpy of dissolution (ΔH diss), enthalpy of formation of aqueous POMs (ΔH f,(aq)), and enthalpy of...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-12, Vol.142 (48), p.20463-20469
Hauptverfasser:	Traustason, Hrafn, Bell, Nicola L, Caranto, Kiana, Auld, David C, Lockey, David T, Kokot, Alex, Szymanowski, Jennifer E.S, Cronin, Leroy, Burns, Peter C
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Cations Cluster chemistry Enthalpy INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY NANOSCIENCE AND NANOTECHNOLOGY RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY Solution chemistry
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