Dihydrogen Adduct (Co–H2) Complexes Displaying H‐Atom and Hydride Transfer

The prototypical reactivity profiles of transition metal dihydrogen complexes (M‐H2) are well‐characterized with respect to oxidative addition (to afford dihydrides, M(H)2) and as acids, heterolytically delivering H+ to a base and H− to the metal. In the course of this study we explored plausible al...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2020-12, Vol.59 (50), p.22631-22637
Hauptverfasser:	Deegan, Meaghan M., Hannoun, Kareem I., Peters, Jonas C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Coordination compounds Dihydrides H-atom transfer H2 activation hydricity Hydrides Hydrogen INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Precursors Thermal stability Transition metals
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