Enhancing the activity of photocatalytic hydrogen evolution from CdSe quantum dots with a polyoxovanadate cluster
Here, we report the improvement of photocatalytic proton reduction using molecular polyoxovanadate-alkoxide clusters as hole scavengers for CdSe quantum dots. The increased hydrogen production is explained by favorable charge interactions between reduced forms of the cluster and the charge on the qu...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-06, Vol.56 (62) |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Edwards, Emily H. Fertig, Alex A. McClelland, Kevin P. Meidenbauer, Mahilet T. Chakraborty, Saikat Krauss, Todd D. Bren, Kara L. Matson, Ellen M. |
| description | Here, we report the improvement of photocatalytic proton reduction using molecular polyoxovanadate-alkoxide clusters as hole scavengers for CdSe quantum dots. The increased hydrogen production is explained by favorable charge interactions between reduced forms of the cluster and the charge on the quantum dots arising from the capping ligands. |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2020-06, Vol.56 (62) |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_osti_scitechconnect_1656794 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | 08 HYDROGEN hole transfer hydrogen production polyoxovanadate quantum dot Solar hydrogen |
| title | Enhancing the activity of photocatalytic hydrogen evolution from CdSe quantum dots with a polyoxovanadate cluster |
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