Chemical Bonding in Colossal Thermopower FeSb2

FeSb2 exhibits a colossal Seebeck coefficient (S ) and a record‐breaking high thermoelectric power factor. It also has an atypical shift from diamagnetism to paramagnetism with increasing temperature, and the fine details of its electron correlation effects have been widely discussed. The extraordin...

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Veröffentlicht in:	Chemistry : a European journal 2020-07, Vol.26 (39), p.8651-8662
Hauptverfasser:	Grønbech, Thomas Bjørn Egede, Tolborg, Kasper, Svendsen, Helle, Overgaard, Jacob, Chen, Yu‐Sheng, Brummerstedt Iversen, Bo
Format:	Artikel
Sprache:	eng
Schlagworte:	antimony Chemical bonds Chemistry Density functional theory Diamagnetism Electron density Electronegativity marcasites Paramagnetism Physical properties Power factor Seebeck effect semiconductors Single crystals Systematic errors thermopower
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