Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework

A thorium–organic framework (TOF-16) containing hexameric secondary building units connected by functionalized binaphthol linkers was synthesized, characterized, and irradiated to probe its radiation resistance. Radiation stability was examined using γ-rays and 5 MeV He2+ ions to simulate α particle...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2020-08, Vol.142 (31), p.13299-13304
Hauptverfasser: Gilson, Sara E, Fairley, Melissa, Julien, Patrick, Oliver, Allen G, Hanna, Sylvia L, Arntz, Grace, Farha, Omar K, LaVerne, Jay A, Burns, Peter C
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 13304
container_issue 31
container_start_page 13299
container_title Journal of the American Chemical Society
container_volume 142
creator Gilson, Sara E
Fairley, Melissa
Julien, Patrick
Oliver, Allen G
Hanna, Sylvia L
Arntz, Grace
Farha, Omar K
LaVerne, Jay A
Burns, Peter C
description A thorium–organic framework (TOF-16) containing hexameric secondary building units connected by functionalized binaphthol linkers was synthesized, characterized, and irradiated to probe its radiation resistance. Radiation stability was examined using γ-rays and 5 MeV He2+ ions to simulate α particles. γ-irradiation of TOF-16 to an unprecedented 4 MGy dose resulted in no apparent bulk structural damage visible by X-ray diffraction. To further probe radiation stability, we conducted the first He2+ ion irradiation study of a metal–organic framework (MOF). Diffraction data indicate onset of crystallinity loss upon approximately 15 MGy of irradiation and total loss of crystallinity upon exposure to approximately 25 MGy of He2+ ion irradiation. The high radiation resistance observed suggests MOFs can withstand radiation exposure at doses found in nuclear waste streams and highlights the need for a systematic approach to understand and eventually design frameworks with exceptional radiation resistance.
doi_str_mv 10.1021/jacs.0c05272
format Article
fullrecord <record><control><sourceid>acs_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_1642447</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a537956327</sourcerecordid><originalsourceid>FETCH-LOGICAL-a389t-1a54f95f48a58c90885d55e5a1363e1dcd9c6f0d9ffc355889fac274ae4f74273</originalsourceid><addsrcrecordid>eNptkL1OwzAURi0EoqWwMaOIiYEU27ETZ4SKAhKoqGrnyPiHuDR2ZbtCbLwDb8iTkCiFienqXp3vk-4B4BTBMYIYXa24CGMoIMUF3gNDRDFMKcL5PhhCCHFasDwbgKMQVu1KMEOHYJDhvGCUlUPwvLQbr4SSykYlkzmXhkfjbDJXwYTIbUwWtfNm23x_ft0Yyzd1rN06eVKRr9vTzL9ya0Qy9bxR786_HYMDzddBnezmCCynt4vJffo4u3uYXD-mPGNlTBGnRJdUE8YpEyVkjEpKFeUoyzOFpJClyDWUpdYio5SxUnOBC8IV0QXBRTYC532vC9FUQZioRC2ctUrECuUEE9JBlz0kvAvBK11tvGm4_6gQrDp7VWev2tlr8bMe32xfGiX_4F9dLXDRA11q5bbeti_-3_UDQdh60w</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework</title><source>American Chemical Society Journals</source><creator>Gilson, Sara E ; Fairley, Melissa ; Julien, Patrick ; Oliver, Allen G ; Hanna, Sylvia L ; Arntz, Grace ; Farha, Omar K ; LaVerne, Jay A ; Burns, Peter C</creator><creatorcontrib>Gilson, Sara E ; Fairley, Melissa ; Julien, Patrick ; Oliver, Allen G ; Hanna, Sylvia L ; Arntz, Grace ; Farha, Omar K ; LaVerne, Jay A ; Burns, Peter C ; Univ. of Notre Dame, IN (United States)</creatorcontrib><description>A thorium–organic framework (TOF-16) containing hexameric secondary building units connected by functionalized binaphthol linkers was synthesized, characterized, and irradiated to probe its radiation resistance. Radiation stability was examined using γ-rays and 5 MeV He2+ ions to simulate α particles. γ-irradiation of TOF-16 to an unprecedented 4 MGy dose resulted in no apparent bulk structural damage visible by X-ray diffraction. To further probe radiation stability, we conducted the first He2+ ion irradiation study of a metal–organic framework (MOF). Diffraction data indicate onset of crystallinity loss upon approximately 15 MGy of irradiation and total loss of crystallinity upon exposure to approximately 25 MGy of He2+ ion irradiation. The high radiation resistance observed suggests MOFs can withstand radiation exposure at doses found in nuclear waste streams and highlights the need for a systematic approach to understand and eventually design frameworks with exceptional radiation resistance.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/jacs.0c05272</identifier><identifier>PMID: 32678589</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; Ions ; Irradiation ; Metal organic frameworks ; NANOSCIENCE AND NANOTECHNOLOGY ; Radiation ; RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY ; Stability</subject><ispartof>Journal of the American Chemical Society, 2020-08, Vol.142 (31), p.13299-13304</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a389t-1a54f95f48a58c90885d55e5a1363e1dcd9c6f0d9ffc355889fac274ae4f74273</citedby><cites>FETCH-LOGICAL-a389t-1a54f95f48a58c90885d55e5a1363e1dcd9c6f0d9ffc355889fac274ae4f74273</cites><orcidid>0000-0003-3153-2416 ; 0000-0002-9904-9845 ; 0000-0002-2319-9628 ; 0000000299049845 ; 0000000331532416 ; 0000000223199628</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jacs.0c05272$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jacs.0c05272$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2763,27074,27922,27923,56736,56786</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32678589$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1642447$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Gilson, Sara E</creatorcontrib><creatorcontrib>Fairley, Melissa</creatorcontrib><creatorcontrib>Julien, Patrick</creatorcontrib><creatorcontrib>Oliver, Allen G</creatorcontrib><creatorcontrib>Hanna, Sylvia L</creatorcontrib><creatorcontrib>Arntz, Grace</creatorcontrib><creatorcontrib>Farha, Omar K</creatorcontrib><creatorcontrib>LaVerne, Jay A</creatorcontrib><creatorcontrib>Burns, Peter C</creatorcontrib><creatorcontrib>Univ. of Notre Dame, IN (United States)</creatorcontrib><title>Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>A thorium–organic framework (TOF-16) containing hexameric secondary building units connected by functionalized binaphthol linkers was synthesized, characterized, and irradiated to probe its radiation resistance. Radiation stability was examined using γ-rays and 5 MeV He2+ ions to simulate α particles. γ-irradiation of TOF-16 to an unprecedented 4 MGy dose resulted in no apparent bulk structural damage visible by X-ray diffraction. To further probe radiation stability, we conducted the first He2+ ion irradiation study of a metal–organic framework (MOF). Diffraction data indicate onset of crystallinity loss upon approximately 15 MGy of irradiation and total loss of crystallinity upon exposure to approximately 25 MGy of He2+ ion irradiation. The high radiation resistance observed suggests MOFs can withstand radiation exposure at doses found in nuclear waste streams and highlights the need for a systematic approach to understand and eventually design frameworks with exceptional radiation resistance.</description><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>Ions</subject><subject>Irradiation</subject><subject>Metal organic frameworks</subject><subject>NANOSCIENCE AND NANOTECHNOLOGY</subject><subject>Radiation</subject><subject>RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY</subject><subject>Stability</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNptkL1OwzAURi0EoqWwMaOIiYEU27ETZ4SKAhKoqGrnyPiHuDR2ZbtCbLwDb8iTkCiFienqXp3vk-4B4BTBMYIYXa24CGMoIMUF3gNDRDFMKcL5PhhCCHFasDwbgKMQVu1KMEOHYJDhvGCUlUPwvLQbr4SSykYlkzmXhkfjbDJXwYTIbUwWtfNm23x_ft0Yyzd1rN06eVKRr9vTzL9ya0Qy9bxR786_HYMDzddBnezmCCynt4vJffo4u3uYXD-mPGNlTBGnRJdUE8YpEyVkjEpKFeUoyzOFpJClyDWUpdYio5SxUnOBC8IV0QXBRTYC532vC9FUQZioRC2ctUrECuUEE9JBlz0kvAvBK11tvGm4_6gQrDp7VWev2tlr8bMe32xfGiX_4F9dLXDRA11q5bbeti_-3_UDQdh60w</recordid><startdate>20200805</startdate><enddate>20200805</enddate><creator>Gilson, Sara E</creator><creator>Fairley, Melissa</creator><creator>Julien, Patrick</creator><creator>Oliver, Allen G</creator><creator>Hanna, Sylvia L</creator><creator>Arntz, Grace</creator><creator>Farha, Omar K</creator><creator>LaVerne, Jay A</creator><creator>Burns, Peter C</creator><general>American Chemical Society</general><general>American Chemical Society (ACS)</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0003-3153-2416</orcidid><orcidid>https://orcid.org/0000-0002-9904-9845</orcidid><orcidid>https://orcid.org/0000-0002-2319-9628</orcidid><orcidid>https://orcid.org/0000000299049845</orcidid><orcidid>https://orcid.org/0000000331532416</orcidid><orcidid>https://orcid.org/0000000223199628</orcidid></search><sort><creationdate>20200805</creationdate><title>Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework</title><author>Gilson, Sara E ; Fairley, Melissa ; Julien, Patrick ; Oliver, Allen G ; Hanna, Sylvia L ; Arntz, Grace ; Farha, Omar K ; LaVerne, Jay A ; Burns, Peter C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a389t-1a54f95f48a58c90885d55e5a1363e1dcd9c6f0d9ffc355889fac274ae4f74273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>Ions</topic><topic>Irradiation</topic><topic>Metal organic frameworks</topic><topic>NANOSCIENCE AND NANOTECHNOLOGY</topic><topic>Radiation</topic><topic>RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gilson, Sara E</creatorcontrib><creatorcontrib>Fairley, Melissa</creatorcontrib><creatorcontrib>Julien, Patrick</creatorcontrib><creatorcontrib>Oliver, Allen G</creatorcontrib><creatorcontrib>Hanna, Sylvia L</creatorcontrib><creatorcontrib>Arntz, Grace</creatorcontrib><creatorcontrib>Farha, Omar K</creatorcontrib><creatorcontrib>LaVerne, Jay A</creatorcontrib><creatorcontrib>Burns, Peter C</creatorcontrib><creatorcontrib>Univ. of Notre Dame, IN (United States)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gilson, Sara E</au><au>Fairley, Melissa</au><au>Julien, Patrick</au><au>Oliver, Allen G</au><au>Hanna, Sylvia L</au><au>Arntz, Grace</au><au>Farha, Omar K</au><au>LaVerne, Jay A</au><au>Burns, Peter C</au><aucorp>Univ. of Notre Dame, IN (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2020-08-05</date><risdate>2020</risdate><volume>142</volume><issue>31</issue><spage>13299</spage><epage>13304</epage><pages>13299-13304</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>A thorium–organic framework (TOF-16) containing hexameric secondary building units connected by functionalized binaphthol linkers was synthesized, characterized, and irradiated to probe its radiation resistance. Radiation stability was examined using γ-rays and 5 MeV He2+ ions to simulate α particles. γ-irradiation of TOF-16 to an unprecedented 4 MGy dose resulted in no apparent bulk structural damage visible by X-ray diffraction. To further probe radiation stability, we conducted the first He2+ ion irradiation study of a metal–organic framework (MOF). Diffraction data indicate onset of crystallinity loss upon approximately 15 MGy of irradiation and total loss of crystallinity upon exposure to approximately 25 MGy of He2+ ion irradiation. The high radiation resistance observed suggests MOFs can withstand radiation exposure at doses found in nuclear waste streams and highlights the need for a systematic approach to understand and eventually design frameworks with exceptional radiation resistance.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>32678589</pmid><doi>10.1021/jacs.0c05272</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-3153-2416</orcidid><orcidid>https://orcid.org/0000-0002-9904-9845</orcidid><orcidid>https://orcid.org/0000-0002-2319-9628</orcidid><orcidid>https://orcid.org/0000000299049845</orcidid><orcidid>https://orcid.org/0000000331532416</orcidid><orcidid>https://orcid.org/0000000223199628</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0002-7863
ispartof Journal of the American Chemical Society, 2020-08, Vol.142 (31), p.13299-13304
issn 0002-7863
1520-5126
language eng
recordid cdi_osti_scitechconnect_1642447
source American Chemical Society Journals
subjects INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Ions
Irradiation
Metal organic frameworks
NANOSCIENCE AND NANOTECHNOLOGY
Radiation
RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
Stability
title Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-13T17%3A25%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Unprecedented%20Radiation%20Resistant%20Thorium%E2%80%93Binaphthol%20Metal%E2%80%93Organic%20Framework&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Gilson,%20Sara%20E&rft.aucorp=Univ.%20of%20Notre%20Dame,%20IN%20(United%20States)&rft.date=2020-08-05&rft.volume=142&rft.issue=31&rft.spage=13299&rft.epage=13304&rft.pages=13299-13304&rft.issn=0002-7863&rft.eissn=1520-5126&rft_id=info:doi/10.1021/jacs.0c05272&rft_dat=%3Cacs_osti_%3Ea537956327%3C/acs_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/32678589&rfr_iscdi=true