Three-Dimensional Phthalocyanine Metal-Catecholates for High Electrochemical Carbon Dioxide Reduction

The synthesis of a new anionic 3D metal-catecholate framework, termed MOF-1992, is achieved by linking tetratopic cobalt phthalocyanin-2,3,9,10,16,17,23,24-octaol linkers with Fe3(−C2O2−)6(OH2)2 trimers into an extended framework of roc topology. MOF-1992 exhibits sterically accessible Co active sit...

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Veröffentlicht in:	Journal of the American Chemical Society 2019-10, Vol.141 (43), p.17081-17085
Hauptverfasser:	Matheu, Roc, Gutierrez-Puebla, Enrique, Monge, M. Ángeles, Diercks, Christian S, Kang, Joohoon, Prévot, Mathieu S, Pei, Xiaokun, Hanikel, Nikita, Zhang, Bing, Yang, Peidong, Yaghi, Omar M
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysts Chemical Sciences crystal structure electrical properties electrodes INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY metal organic frameworks
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