An unexpected rhenium(IV)-rhenium(VII) salt: [Co(NH 3 ) 6 ] 3 [Re VII O 4 ][Re IV F 6 ] 4 ·6H 2 O
The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K ReF starting material with KReO . It consists of octa-hedral [Co(NH ) ] cation (Co1 site symmetry 1), tetra-hedr...
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| Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-08, Vol.75 (Pt 8), p.1158-1161 |
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| container_issue | Pt 8 |
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| container_title | Acta crystallographica. Section E, Crystallographic communications |
| container_volume | 75 |
| creator | Louis-Jean, James Mariappan Balasekaran, Samundeeswari Hagenbach, Adelheid Poineau, Frederic |
| description | The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K
ReF
starting material with KReO
. It consists of octa-hedral [Co(NH
)
]
cation (Co1 site symmetry 1), tetra-hedral [Re
O
]
anions (Re site symmetry 1) and octa-hedral [Re
F
]
anions (Re site symmetries 1and ). The [ReF
]
octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH
)
]
octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO
]
tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin. |
| doi_str_mv | 10.1107/S2056989019009757 |
| format | Article |
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ReF
starting material with KReO
. It consists of octa-hedral [Co(NH
)
]
cation (Co1 site symmetry 1), tetra-hedral [Re
O
]
anions (Re site symmetry 1) and octa-hedral [Re
F
]
anions (Re site symmetries 1and ). The [ReF
]
octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH
)
]
octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO
]
tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.</description><identifier>ISSN: 2056-9890</identifier><identifier>EISSN: 2056-9890</identifier><identifier>DOI: 10.1107/S2056989019009757</identifier><identifier>PMID: 31417784</identifier><language>eng</language><publisher>England: International Union of Crystallography (IUCr)</publisher><ispartof>Acta crystallographica. Section E, Crystallographic communications, 2019-08, Vol.75 (Pt 8), p.1158-1161</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1404-f4ca53102d85cbf91487b6dc2fcd162562c196dd6ae04cdf819998647278e8f3</citedby><cites>FETCH-LOGICAL-c1404-f4ca53102d85cbf91487b6dc2fcd162562c196dd6ae04cdf819998647278e8f3</cites><orcidid>0000-0002-7711-0967 ; 0000000277110967</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,864,885,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31417784$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1617940$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Louis-Jean, James</creatorcontrib><creatorcontrib>Mariappan Balasekaran, Samundeeswari</creatorcontrib><creatorcontrib>Hagenbach, Adelheid</creatorcontrib><creatorcontrib>Poineau, Frederic</creatorcontrib><title>An unexpected rhenium(IV)-rhenium(VII) salt: [Co(NH 3 ) 6 ] 3 [Re VII O 4 ][Re IV F 6 ] 4 ·6H 2 O</title><title>Acta crystallographica. Section E, Crystallographic communications</title><addtitle>Acta Crystallogr E Crystallogr Commun</addtitle><description>The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K
ReF
starting material with KReO
. It consists of octa-hedral [Co(NH
)
]
cation (Co1 site symmetry 1), tetra-hedral [Re
O
]
anions (Re site symmetry 1) and octa-hedral [Re
F
]
anions (Re site symmetries 1and ). The [ReF
]
octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH
)
]
octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO
]
tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.</description><issn>2056-9890</issn><issn>2056-9890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNplUE1Lw0AQXUSxUvsDvMjgqT1Ed5LNfngrxdpAsaCll1JCsruhkTYp2RT0l3n3l5lYK4KnefM-BuYRcoX0FpGKuxefhlxJRVFRqkQoTshFS3ktd_oHd0jPuVdKKbIw4KF_TjoBMhRCsguSDgvYF_ZtZ3VtDVRrW-T7bT9aDLwjXkTRAFyyqe9hOSr7TxMIYAAcVs1cPltodJgBg1W7RAsYf2sMPj_4BHyYXZKzLNk42_uZXTIfP8xHE286e4xGw6mnkVHmZUwnYYDUNzLUaaaQSZFyo_1MG-R-yH2NihvDE0uZNplEpZTkTPhCWpkFXXJzOFu6Oo-dzmur17osiuazGDkKxWhjwoNJV6Vzlc3iXZVvk-o9Rhq3tcb_am0y14fMbp9urflNHEsMvgBCAGqt</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Louis-Jean, James</creator><creator>Mariappan Balasekaran, Samundeeswari</creator><creator>Hagenbach, Adelheid</creator><creator>Poineau, Frederic</creator><general>International Union of Crystallography (IUCr)</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-7711-0967</orcidid><orcidid>https://orcid.org/0000000277110967</orcidid></search><sort><creationdate>20190801</creationdate><title>An unexpected rhenium(IV)-rhenium(VII) salt: [Co(NH 3 ) 6 ] 3 [Re VII O 4 ][Re IV F 6 ] 4 ·6H 2 O</title><author>Louis-Jean, James ; Mariappan Balasekaran, Samundeeswari ; Hagenbach, Adelheid ; Poineau, Frederic</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1404-f4ca53102d85cbf91487b6dc2fcd162562c196dd6ae04cdf819998647278e8f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Louis-Jean, James</creatorcontrib><creatorcontrib>Mariappan Balasekaran, Samundeeswari</creatorcontrib><creatorcontrib>Hagenbach, Adelheid</creatorcontrib><creatorcontrib>Poineau, Frederic</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Louis-Jean, James</au><au>Mariappan Balasekaran, Samundeeswari</au><au>Hagenbach, Adelheid</au><au>Poineau, Frederic</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An unexpected rhenium(IV)-rhenium(VII) salt: [Co(NH 3 ) 6 ] 3 [Re VII O 4 ][Re IV F 6 ] 4 ·6H 2 O</atitle><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle><addtitle>Acta Crystallogr E Crystallogr Commun</addtitle><date>2019-08-01</date><risdate>2019</risdate><volume>75</volume><issue>Pt 8</issue><spage>1158</spage><epage>1161</epage><pages>1158-1161</pages><issn>2056-9890</issn><eissn>2056-9890</eissn><abstract>The title hydrated salt, tris-[hexa-amminecobalt(III)] tetraoxidorhenate(VII) tetra-kis-[hexa-fluorido-rhenate(IV)] hexa-hydrate, arose unexpectedly due to possible contamination of the K
ReF
starting material with KReO
. It consists of octa-hedral [Co(NH
)
]
cation (Co1 site symmetry 1), tetra-hedral [Re
O
]
anions (Re site symmetry 1) and octa-hedral [Re
F
]
anions (Re site symmetries 1and ). The [ReF
]
octa-hedral anions (mean Re-F = 1.834 Å), [Co(NH
)
]
octa-hedral cations (mean Co-N = 1.962 Å), and the [ReO
]
tetra-hedral anion (mean Re-O = 1.719 Å) are slightly distorted. A network of N-H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.</abstract><cop>England</cop><pub>International Union of Crystallography (IUCr)</pub><pmid>31417784</pmid><doi>10.1107/S2056989019009757</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-7711-0967</orcidid><orcidid>https://orcid.org/0000000277110967</orcidid></addata></record> |
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| issn | 2056-9890 2056-9890 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1617940 |
| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; PubMed Central; Free Full-Text Journals in Chemistry |
| title | An unexpected rhenium(IV)-rhenium(VII) salt: [Co(NH 3 ) 6 ] 3 [Re VII O 4 ][Re IV F 6 ] 4 ·6H 2 O |
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