Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions

Redox-active proanions of the type B12(OCH2Ar)12 [Ar = C6F5 (1), 4-CF3C6H4 (2), 3,5-(CF3)2C6H3 (3)] are introduced in the context of an experimental and computational study of the visible-light-initiated polymerization of a family of styrenes. Neutral, air-stable proanions 1–3 were found to initiate...

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Veröffentlicht in:	Inorganic chemistry 2019-08, Vol.58 (16), p.10516-10526
Hauptverfasser:	Axtell, Jonathan C, Messina, Marco S, Liu, Ji-Yuan, Galaktionova, Daria, Schwan, Josef, Porter, Tyler M, Savage, Miles D, Wixtrom, Alex I, Rheingold, Arnold L, Kubiak, Clifford P, Winkler, Jay R, Gray, Harry B, Král, Petr, Alexandrova, Anastassia N, Spokoyny, Alexander M
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry
Online-Zugang:	Volltext
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