Direct Anti-Markovnikov Addition of Water to Olefin To Synthesize Primary Alcohols: A Theoretical Study

Anti-Markovnikov addition of water to olefins has been a long-standing goal in catalysis. The [Rh­(COD)­(DPEphos)]+ complex was found as a general and regioselective group 9 catalyst for intermolecular hydroamination of alkenes. The reaction mechanism was adapted for intermolecular hydration of alke...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2019-01, Vol.123 (4), p.958-965
Hauptverfasser:	Ceylan, Yavuz S, Cundari, Thomas R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Physics
Online-Zugang:	Volltext
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