Second Coordination Sphere Effects in an Evolved Ru Complex Based on Highly Adaptable Ligand Results in Rapid Water Oxidation Catalysis

A new Ru complex containing the deprotonated 2,2′:6′,2′′-terpyridine-6,6′′-diphosphonic acid (H4tPa) and pyridine (py) of general formula [RuII(H3tPa-κ-N3O)­(py)2]+, 2 +, has been prepared and thoroughly characterized by means of spectroscopic and electrochemical techniques, X-ray diffraction analys...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-03, Vol.142 (11), p.5068-5077
Hauptverfasser:	Vereshchuk, Nataliia, Matheu, Roc, Benet-Buchholz, Jordi, Pipelier, Muriel, Lebreton, Jacques, Dubreuil, Didier, Tessier, Arnaud, Gimbert-Suriñach, Carolina, Ertem, Mehmed Z, Llobet, Antoni
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Chemical Sciences INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Ligands Organophosphorus compounds Redox reactions Water Oxidation
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