On the formation of ethynylbiphenyl (C14D5H5; C6D5C6H4CCH) isomers in the reaction of D5-phenyl radicals (C6D5; X2A1) with phenylacetylene (C6H5C2H; X1A1) under single collision conditions

[Display omitted] •Ethynylbiphenyls formed in the reaction of phenyl radicals with phenylacetylene.•No phenanthrene formed at collision energy of 121kJmol−1.•Ethynylbiphenyls are formed in exothermic reactions by hydrogen atom emission. Reaction dynamics of the D5-phenyl radical with phenylacetylene...

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Veröffentlicht in:Chemical physics letters 2014-03, Vol.595-596 (C), p.230-236
Hauptverfasser: Parker, Dorian S.N., Yang, Tao, Kaiser, Ralf I., Landera, Alexander, Mebel, Alexander M.
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Sprache:eng
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