One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium4+ Complex
Here, two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R-3, is built up of isolated GeO4 units, and contains a complex a...
Gespeichert in:
| Veröffentlicht in: | Inorganic chemistry 2017-05, Vol.56 (11) |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 11 |
| container_start_page | |
| container_title | Inorganic chemistry |
| container_volume | 56 |
| creator | Fulle, Kyle Sanjeewa, Liurukara D. McMillen, Colin D. Wen, Yimei Rajamanthrilage, Apeksha C. Anker, Jeffrey N. Chumanov, George Kolis, Joseph W. |
| description | Here, two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R-3, is built up of isolated GeO4 units, and contains a complex arrangement of terbium oxide polyhedra. K2TbGe2O7 is a terbium(4+) pyrogermanate that is isostructural with K2ZrGe2O7 and exhibits a rare stable Tb4+ oxidation state in the solid state. |
| format | Article |
| fullrecord | <record><control><sourceid>osti</sourceid><recordid>TN_cdi_osti_scitechconnect_1596455</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1596455</sourcerecordid><originalsourceid>FETCH-osti_scitechconnect_15964553</originalsourceid><addsrcrecordid>eNqNi9FqwjAYRsNQWNW9w8-uFCkkbRPpbmXa4kUEy9idpPUXM9rEJRH07a3gA3h1DpzveyMR4wmNOaO_AxJR2jsTIn8nI-__KKV5momI_EuD8dYGKG4HZ8MJXada2N1Mr157sEeo6rIsWTpdo8xmQi6mspiBMgfYJH36WWMiF1-wdXhWTgVtzeOkYBdU3SJU6Gp96bI5LG13bvE6IcOjaj1-PDkmn6vvalnE1ge9940O2Jwaaww2Yc94LjLO05dGd1UVSBk</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium4+ Complex</title><source>American Chemical Society Journals</source><creator>Fulle, Kyle ; Sanjeewa, Liurukara D. ; McMillen, Colin D. ; Wen, Yimei ; Rajamanthrilage, Apeksha C. ; Anker, Jeffrey N. ; Chumanov, George ; Kolis, Joseph W.</creator><creatorcontrib>Fulle, Kyle ; Sanjeewa, Liurukara D. ; McMillen, Colin D. ; Wen, Yimei ; Rajamanthrilage, Apeksha C. ; Anker, Jeffrey N. ; Chumanov, George ; Kolis, Joseph W. ; Clemson Univ., SC (United States)</creatorcontrib><description>Here, two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R-3, is built up of isolated GeO4 units, and contains a complex arrangement of terbium oxide polyhedra. K2TbGe2O7 is a terbium(4+) pyrogermanate that is isostructural with K2ZrGe2O7 and exhibits a rare stable Tb4+ oxidation state in the solid state.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><language>eng</language><publisher>United States: American Chemical Society (ACS)</publisher><subject>Hydrothermal synthesis ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; rare-earth germanate ; terbium oxidation</subject><ispartof>Inorganic chemistry, 2017-05, Vol.56 (11)</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000000277738797</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1596455$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Fulle, Kyle</creatorcontrib><creatorcontrib>Sanjeewa, Liurukara D.</creatorcontrib><creatorcontrib>McMillen, Colin D.</creatorcontrib><creatorcontrib>Wen, Yimei</creatorcontrib><creatorcontrib>Rajamanthrilage, Apeksha C.</creatorcontrib><creatorcontrib>Anker, Jeffrey N.</creatorcontrib><creatorcontrib>Chumanov, George</creatorcontrib><creatorcontrib>Kolis, Joseph W.</creatorcontrib><creatorcontrib>Clemson Univ., SC (United States)</creatorcontrib><title>One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium4+ Complex</title><title>Inorganic chemistry</title><description>Here, two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R-3, is built up of isolated GeO4 units, and contains a complex arrangement of terbium oxide polyhedra. K2TbGe2O7 is a terbium(4+) pyrogermanate that is isostructural with K2ZrGe2O7 and exhibits a rare stable Tb4+ oxidation state in the solid state.</description><subject>Hydrothermal synthesis</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>rare-earth germanate</subject><subject>terbium oxidation</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNi9FqwjAYRsNQWNW9w8-uFCkkbRPpbmXa4kUEy9idpPUXM9rEJRH07a3gA3h1DpzveyMR4wmNOaO_AxJR2jsTIn8nI-__KKV5momI_EuD8dYGKG4HZ8MJXada2N1Mr157sEeo6rIsWTpdo8xmQi6mspiBMgfYJH36WWMiF1-wdXhWTgVtzeOkYBdU3SJU6Gp96bI5LG13bvE6IcOjaj1-PDkmn6vvalnE1ge9940O2Jwaaww2Yc94LjLO05dGd1UVSBk</recordid><startdate>20170524</startdate><enddate>20170524</enddate><creator>Fulle, Kyle</creator><creator>Sanjeewa, Liurukara D.</creator><creator>McMillen, Colin D.</creator><creator>Wen, Yimei</creator><creator>Rajamanthrilage, Apeksha C.</creator><creator>Anker, Jeffrey N.</creator><creator>Chumanov, George</creator><creator>Kolis, Joseph W.</creator><general>American Chemical Society (ACS)</general><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000000277738797</orcidid></search><sort><creationdate>20170524</creationdate><title>One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium4+ Complex</title><author>Fulle, Kyle ; Sanjeewa, Liurukara D. ; McMillen, Colin D. ; Wen, Yimei ; Rajamanthrilage, Apeksha C. ; Anker, Jeffrey N. ; Chumanov, George ; Kolis, Joseph W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_15964553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Hydrothermal synthesis</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>rare-earth germanate</topic><topic>terbium oxidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fulle, Kyle</creatorcontrib><creatorcontrib>Sanjeewa, Liurukara D.</creatorcontrib><creatorcontrib>McMillen, Colin D.</creatorcontrib><creatorcontrib>Wen, Yimei</creatorcontrib><creatorcontrib>Rajamanthrilage, Apeksha C.</creatorcontrib><creatorcontrib>Anker, Jeffrey N.</creatorcontrib><creatorcontrib>Chumanov, George</creatorcontrib><creatorcontrib>Kolis, Joseph W.</creatorcontrib><creatorcontrib>Clemson Univ., SC (United States)</creatorcontrib><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fulle, Kyle</au><au>Sanjeewa, Liurukara D.</au><au>McMillen, Colin D.</au><au>Wen, Yimei</au><au>Rajamanthrilage, Apeksha C.</au><au>Anker, Jeffrey N.</au><au>Chumanov, George</au><au>Kolis, Joseph W.</au><aucorp>Clemson Univ., SC (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium4+ Complex</atitle><jtitle>Inorganic chemistry</jtitle><date>2017-05-24</date><risdate>2017</risdate><volume>56</volume><issue>11</issue><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Here, two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R-3, is built up of isolated GeO4 units, and contains a complex arrangement of terbium oxide polyhedra. K2TbGe2O7 is a terbium(4+) pyrogermanate that is isostructural with K2ZrGe2O7 and exhibits a rare stable Tb4+ oxidation state in the solid state.</abstract><cop>United States</cop><pub>American Chemical Society (ACS)</pub><orcidid>https://orcid.org/0000000277738797</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0020-1669 |
| ispartof | Inorganic chemistry, 2017-05, Vol.56 (11) |
| issn | 0020-1669 1520-510X |
| language | eng |
| recordid | cdi_osti_scitechconnect_1596455 |
| source | American Chemical Society Journals |
| subjects | Hydrothermal synthesis INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY rare-earth germanate terbium oxidation |
| title | One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium4+ Complex |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T22%3A08%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-osti&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=One-Pot%20Hydrothermal%20Synthesis%20of%20TbIII13(GeO4)6O7(OH)%20and%20K2TbIVGe2O7:%20Preparation%20of%20a%20Stable%20Terbium4+%20Complex&rft.jtitle=Inorganic%20chemistry&rft.au=Fulle,%20Kyle&rft.aucorp=Clemson%20Univ.,%20SC%20(United%20States)&rft.date=2017-05-24&rft.volume=56&rft.issue=11&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/&rft_dat=%3Costi%3E1596455%3C/osti%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |