Hydrothermal synthesis of lanthanide rhenium oxides: Structures and magnetism of Ln2Re2O7(OH) (Ln = Pr, Nd) and Ln4Re2O11 (Ln = Eu, Tb)

The reactions of Ln2O3 (Ln = LaLu) with ReO2 were examined in high temperature hydrothermal water (650 °C). In all cases the rhenium oxide was added in a three-fold excess. No external mineralizer was needed and the rhenate itself acted as a sufficient mineralizer to form high quality single crystal...

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Veröffentlicht in:	Journal of solid state chemistry 2019-07, Vol.275 (C), p.149-158
Hauptverfasser:	Kolambage, Mudithangani T.K., McMillen, Colin D., McGuire, Michael A., Sanjeewa, Liurukara D., Ivey, Kimberly, Wen, Yimei, Chumanov, George, Kolis, Joseph W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystal Growth Hydrothermal Lanthanide Magnetism MATERIALS SCIENCE Rare Earths Rhenate Rhenium Oxides
Online-Zugang:	Volltext
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